Journal article
Half-Calcium Substitution of the CaB₆ Surface with Hydrogen: Synthesis, Structural Characterization, and Electronic Structure
Hikari Yoshioka
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Mitsuhiro Saito
(author)
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Institute of Engineering Innovation, School of Engineering The University of Tokyo
Satoshi Tominaka
(author)
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Center for Basic Research on Materials/Advanced Materials Characterization Field/Quantum Beam Diffraction Group, National Institute for Materials Science
;
Susumu Okada
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Mina Maruyama
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Yanlin Gao
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Ben Slater
(author)
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Dept of Chemistry University College London
Shin-ichi Ito
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Miwa Hikichi
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Ryuki Tsuji
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Osamu Oki
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Yuichi Ikuhara
(author)
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Institute of Engineering Innovation, School of Engineering The University of Tokyo
Shin-ichi Orimo
(author)
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Advanced Institute for Materials Research (AIMR) Tohoku University
Hideo Hosono
(author)
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Research Center for Materials Nanoarchitectonics (MANA)/Nanomaterials Field/ElectroActive Materials Team, National Institute for Materials Science
;
Takahiro Kondo
(author)
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Institute of Pure and Applied Sciences University of Tsukuba
Collection
Citation
Hikari Yoshioka, Mitsuhiro Saito, Satoshi Tominaka, Susumu Okada, Mina Maruyama, Yanlin Gao, Ben Slater, Shin-ichi Ito, Miwa Hikichi, Ryuki Tsuji, Osamu Oki, Yuichi Ikuhara, Shin-ichi Orimo, Hideo Hosono, Takahiro Kondo.
Half-Calcium Substitution of the CaB₆ Surface with Hydrogen: Synthesis, Structural Characterization, and Electronic Structure.
SMALL STRUCTURES.
2025,
6
(11),
.
https://doi.org/10.1002/sstr.202500389
Description:
(abstract)過去に論文報告したホウ化水素は二次元の化合物であったが、この研究では３次元の構造体になります。以前はMgB2をイオン置換して、HBとしていたものと、CaB6のイオン交換と構造解析をしている仕事です。バルクではイオン交換が進まず、表面のみであるが特異な構造が得られた。
Rights:
Keyword: hydrogen boride, ion exchange, crystal structure
Date published: 2025-09-12
Publisher: Wiley-VCH GmbH
Journal:
- SMALL STRUCTURES (ISSN: 26884062) vol. 6 issue. 11
Funding:
- JSPS Grant Nos. JP19H02551, JP19H05046:A01, JP21H00015:B01, JP21H05012, JP21H05232, JP21H05233, JP21K14484, JP22H00283, JP22K18964, JP23H05469, JP23H01843, JP23K26536, JP24H02204, JP25H00417, and JP25K08414 (KAKENHI)
- MEXT Element Strategy Initiative to Form Core Research Center JPMXP0112101001
- JST CREST Program Japan Grant No. JPMJCR21O4, JPMJCR24A2, JPMJCR24A4, and JPMJCR23A4
Manuscript type: Author's version (Accepted manuscript)
MDR DOI: https://doi.org/10.48505/nims.6012
First published URL: https://doi.org/10.1002/sstr.202500389
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Updated at: 2025-12-15 13:49:38 +0900
Published on MDR: 2025-12-18 19:08:27 +0900
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