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Description:

　For the extraction of hydrogen from ammonia (NH3) at low temperatures, we have investigated the Ni-based catalysts fabricated by the thermal decomposition of RNi5 intermetallics (R = Ce or Y). The interconnected microstructure formed via phase separation between the Ni catalyst and the resulting oxide supporter was observed to evolve via the low-temperature thermal decomposition of RNi5. The resulting Ni/CeO2 nanocomposite exhibited a superior catalytic activity of ~25% at 400 ℃ for NH3 cracking.

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• In Copyright
  

  This document is the Accepted Manuscript version of a Published Work that appeared in final form in Ammonia cracking catalyzed by Ni nanoparticles confined in the framework of CeO2 support, copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpclett.3c02446.

Keyword: ammonia cracking, ammonia decomposition, intermetallics

Date published: 2023-10-26

Publisher: American Chemical Society

Journal:

• Journal of Physical Chemistry Letters vol. 14 p. 9516-9520

Funding:

• 日本学術振興会 科学研究費助成事業 基盤研究(B) 22H02172 (水素と親和性の高い金属間化合物電子化物の探索：軟らかさからの新アプロ-チ )
• フジクラ財団 2023年度研究助成 フ財23-006 (アンモニア分解用触媒の探索)
• 泉科学技術振興財団 2022-J-042 (金属間化合物触媒の探索 )

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4250

First published URL: https://doi.org/10.1021/acs.jpclett.3c02446

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Contact agent: 溝口拓 (Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)) mizoguchi.hiroshi@nims.go.jp

Updated at: 2024-10-18 16:30:22 +0900

Published on MDR: 2024-10-18 16:30:23 +0900