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Alternative title: ビトリマーの粘弾性効果に対するテレケリックポリマー原料の効果

Description:

結合交代性を有する架橋高分子材料ビトリマーについて、合成原料として架橋反応点の位置が規定されたテレケリックポリマーを用いた場合、反応点が規定されていないランダムポリマーに対して大きく粘弾性特性が異なることを明らかにした。テレケリックポリマーから得られたビトリマーは昇温により大きな弾性率の減少を示し流体と同様の性質を持った。

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• Creative Commons BY Attribution 4.0 International
  

  This is the peer reviewed version of the following article: [Nakamura, Y., et al. M.,Impact of Telechelic Polymer Precursors on the Viscoelastic Properties of Vitrimers], which has been published in final form at  https://doi.org/10.1002/macp.202100433. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

Keyword: Vitrimer, Crosslink polymer, Viscoelasticity, Telechelic polymer, Dynamic covalent bond, Reversible-deactivation radical polymerization

Date published: 2022-03-09

Publisher: Wiley

Journal:

• MACROMOLECULAR CHEMISTRY AND PHYSICS (ISSN: 10221352) vol. 223 issue. 7 p. 2100433-2100433

Funding:

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.3865

First published URL: https://doi.org/10.1002/macp.202100433

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Updated at: 2024-01-05 22:13:47 +0900

Published on MDR: 2023-03-29 15:57:53 +0900