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説明:

Although nucleation is considered the first step in the crystallization of glass materials, the structure and properties of the nuclei are not understood well. Influence of nucleation on the structure and dynamics of celecoxib glass was evaluated in this study. The nuclei for Form III were induced by annealing the glass at freezing temperature, and their impact on the relaxation behavior was investigated using thermal analysis and broadband dielectric spectroscopy to find accelerated α relaxation and suppressed β relaxation.

権利情報:

• In Copyright
  This document is the Accepted Manuscript version of a Published Work that appeared in final form in Molecular Pharmaceutics, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.molpharmaceut.3c01116

キーワード: Glass, Nucleation, Crystallization, Relaxation, Cooperative rearranging region

刊行年月日: 2024-04-01

出版者: American Chemical Society (ACS)

掲載誌:

• Molecular Pharmaceutics (ISSN: 15438392) vol. 21 issue. 4 p. 1794-1803

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4687

公開URL: https://doi.org/10.1021/acs.molpharmaceut.3c01116

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更新時刻: 2025-02-24 12:30:14 +0900

MDRでの公開時刻: 2025-02-24 12:30:15 +0900