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Ion-pairing assemblies of π-extended anion-responsive organoplatinum complexes

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PtII complexes of π-extended dipyrrolyldiketones were synthesized as anion-responsive π-electronic molecules. The dipyrrolyldiketone PtII complexes exhibited red-shifted absorption and photoluminescence properties. In the solid state, [1 + 1]-type anion complexes formed charge-by-charge ion-pairing assemblies when combined with countercations. Detailed theoretical studies of the packing structures revealed favorable interactions between the planar anion complexes and π-electronic cations.

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  • Name
    Yohei Haketa
    Role
    author
    Name
    Yu Murakami
    Role
    author
    Name
    Hiromitsu Maeda
    Organization
    Ritsumeikan University
    Sub organization
    Department of Applied Chemistry, College of Life Sciences
    Role
    author
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  • 26/02/2024
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  • Accepted manuscript
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