Download file (2.03 MB)
Download as zip (1.77 MB)

Collection

Citation

Description:

The emergence of macroscopic self-propelled oscillatory motion based on molecular design has attracted continual attention in relation to autonomous systems in living organisms. Herein, a series of perylenediimides (PDIs) with various imide side chains was prepared to explore the impact of molecular design and alignment on the self-propelled motion at the air–water interface. When placed on an aqueous solution containing a reductant, a solid disk of neutral PDI was reduced to form the water soluble, surface-active PDI dianion species, which induces a surface tension gradient in the vicinity of the disk for self-propelled motion. We found that centimeter-scale oscillatory motion could be elicited by controlling the supply rate of PDI dianion species through the reductant concentration and the structure of imide side chains. Furthermore, we found that the onset and speed of the self-propelled motion could be changed by the crystallinity of PDI at the water surface. This design principle using π-conjugated molecules and their self-assemblies could advance self-propelled, non-equilibrium systems powered by chemical energy.

Rights:

• Creative Commons BY-NC-ND Attribution-NonCommercial-NoDerivs 4.0 International
  

Keyword: Perylene dyes, Nonequilibrium processes, Reduction, Marangoni flow, Oscillatory motion

Date published: 2024-11-11

Publisher: Wiley-Blackwell

Journal:

• ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (ISSN: 14337851) vol. 63 issue. 46

Funding:

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1002/anie.202410671

Related item:

Other identifier(s):

Contact agent:

Updated at: 2024-11-07 16:30:23 +0900

Published on MDR: 2024-11-07 16:30:24 +0900