Yu Wen
;
Ayako Hashimoto
(National Institute for Materials Science)
;
Akihiko Hirata
;
Hideki Abe
(National Institute for Materials Science)
Description:
(abstract)Homology analysis is an efficient topological method of interpreting the shape of data. Several researches have applied it to describe and classify material structures, including metallic glasses and polycrystals. A quantitative interpretation of structures is necessary to find correlation in the structure-property relationship, which can be accomplished using the Betti numbers, βi. In the case of a two-dimensional (2D) structure image, the essential structure information, such as connectivity components and 1D holes, can be extracted and represented by β0 and β1, respectively. Via STEM images, we previously showed that the connectivity of the CeO2 phase, β0, plays an important role in the oxygen ionic transportation of Pt/CeO2 composites. However, this dependence does not work for the network structure, because isolated CeO2 phases might be connected three-dimensionally. Therefore, 3D structural analysis is necessary for network structures to verify the relationship between the CeO2 connectivity and ionic conductivity.
Rights:
Keyword: Betti number, Metal-oxide nanocomposite, STEM tomography, Ionic conductivity
Date published: 2021-07-30
Publisher: Oxford University Press (OUP)
Journal:
Funding:
Manuscript type: Author's version (Accepted manuscript)
MDR DOI: https://doi.org/10.48505/nims.5170
First published URL: https://doi.org/10.1017/s1431927621010345
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Updated at: 2024-12-18 16:31:18 +0900
Published on MDR: 2024-12-18 16:31:18 +0900
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