Download all files (3.11MB)

コレクション

引用

説明:

It is shown that, as in the case of block copolymerization in covalent polymer chemistry, the order of the polymerization of two monomers has a critical effect in the synthesis of 2D block copolymers of porphyrin-based monomers. In one of the orders of polymerization, secondary nucleation is involved, leading to nanosheets with uncontrolled areas and edge roughness.

権利情報:

• In Copyright
  

  This is the peer reviewed version of the following article: Jin, Z., Takeuchi, M., Wakayama, Y. and Sugiyasu, K. (2025), Polymerization Order in the Synthesis of 2D Block Supramolecular Copolymers. Chem. Eur. J., 31: e01739, which has been published in final form at https://doi.org/10.1002/chem.202501739. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

キーワード: supramolecular polymerization, block copolymerization

刊行年月日: 2025-08-13

出版者: Wiley

掲載誌:

• Chemistry – A European Journal (ISSN: 09476539) vol. 31 issue. 45 e01739

研究助成金:

• Samco Foundation
• Mitsubishi Foundation
• Sekisui Chemical
• Japan Science and Technology Corporation JPMJCR23L2

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5670

公開URL: https://doi.org/10.1002/chem.202501739

関連資料:

その他の識別子:

連絡先:

更新時刻: 2025-08-25 14:35:12 +0900

MDRでの公開時刻: 2026-07-21 08:29:33 +0900