Article X-ray Absorption Spectroscopic Study of the Transition-Metal-Only Double Perovskite Oxide Mn2CoReO6

Xiao Wang ORCID ; Jie Zhang ORCID ; Zhao Pan ORCID ; Dabiao Lu ORCID ; Maocai Pi ; Xubin Ye ORCID ; Cheng Dong ; Jie Chen ORCID ; Kai Chen ; Florin Radu ; Sonia Francoual ; Stefano Agrestini ORCID ; Zhiwei Hu ORCID ; Chun-Fu Chang ; Arata Tanaka ; Kazunari Yamaura SAMURAI ORCID (National Institute for Materials ScienceROR) ; Yao Shen ; Youwen Long ORCID

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Xiao Wang, Jie Zhang, Zhao Pan, Dabiao Lu, Maocai Pi, Xubin Ye, Cheng Dong, Jie Chen, Kai Chen, Florin Radu, Sonia Francoual, Stefano Agrestini, Zhiwei Hu, Chun-Fu Chang, Arata Tanaka, Kazunari Yamaura, Yao Shen, Youwen Long. X-ray Absorption Spectroscopic Study of the Transition-Metal-Only Double Perovskite Oxide Mn2CoReO6. The Journal of Physical Chemistry C. 2024, 128 (37), 15668-15675. https://doi.org/10.1021/acs.jpcc.4c04491

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(abstract)

By means of x-ray absorption spectroscopic studies, both experimentally and theoretically, we investigated the magnetic properties of the transition-metal-only double perovskite oxide Mn2CoReO6, which experiences an antiferromagnetic transition at TN = 93 K whereas holds a considerable net moment at low temperature. Internal magnetic fields against the applied magnetic field for all the transition metal ions were identified, providing a microscopic insight of the intra-site antiferromagnetic couplings. Nevertheless, parallelly oriented canted spins of the Mn, Co and Re cations were observed. In particularly, the Mn and Co cations hold considerable canting moments, which can be ascribed to the competition between the ferromagnetic inter-site and antiferromagnetic intra-site magnetic interactions. Moreover, a linear magnetoresistance effect was observed below TN. The concurrence of the magnetoresistance effect and the antiferromagnetic nature make Mn2CoReO6 a promising candidate for high-speed and energy-saving spintronics applications.

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  • In Copyright

    This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry C, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpcc.4c04491

Keyword: Double perovskite oxides, Mn2CoReO6

Date published: 2024-09-19

Publisher: American Chemical Society (ACS)

Journal:

  • The Journal of Physical Chemistry C (ISSN: 19327447) vol. 128 issue. 37 p. 15668-15675

Funding:

  • National Key Research and Development Program of China 2021YFA1400300
  • Deutsche Forschungsgemeinschaft SFB 1143
  • Natural Science Foundation of Beijing Municipality Z200007
  • National Natural Science Foundation of China 11921004
  • National Natural Science Foundation of China 11934017
  • National Natural Science Foundation of China 12261131499
  • National Natural Science Foundation of China 12304159
  • Chinese Academy of Sciences XDB33000000
  • National Natural Science Foundation of China 12304268

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4768

First published URL: https://doi.org/10.1021/acs.jpcc.4c04491

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Updated at: 2025-09-10 08:30:43 +0900

Published on MDR: 2025-09-10 08:22:27 +0900

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