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Description:

A racemic mixture of N-Fmoc-protected phenylalanine or tryptophan was found to spontaneously afford a gel enriched in either L- or D-form of their enantiomers stochastically. Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the observed phenomenon.

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• In Copyright
  

Keyword: Chiral Symmetry Breaking, Gel, Secondary Nucleation

Date published: 2024-11-01

Publisher: Royal Society of Chemistry (RSC)

Journal:

• Nanoscale (ISSN: 20403364) vol. 16 issue. 47

Funding:

• Japan Society for the Promotion of Science JP23K04844

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5110

First published URL: https://doi.org/10.1039/d4nr04011b

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Updated at: 2025-11-04 08:30:10 +0900

Published on MDR: 2025-11-02 08:22:11 +0900