論文 Macroscopic chiral symmetry breaking in gelation of Fmoc-amino acids: homochiral selective secondary nucleation promoted by the choice of solvent or stirring

Kentaro Tashiro SAMURAI ORCID

コレクション

引用
Kentaro Tashiro. Macroscopic chiral symmetry breaking in gelation of Fmoc-amino acids: homochiral selective secondary nucleation promoted by the choice of solvent or stirring. Nanoscale. 2024, 16 (47), . https://doi.org/10.1039/d4nr04011b

説明:

(abstract)

A racemic mixture of N-Fmoc-protected phenylalanine or tryptophan was found to spontaneously afford a gel enriched in either L- or D-form of their enantiomers stochastically. Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the observed phenomenon.

権利情報:

キーワード: Chiral Symmetry Breaking, Gel, Secondary Nucleation

刊行年月日: 2024-11-01

出版者: Royal Society of Chemistry (RSC)

掲載誌:

  • Nanoscale (ISSN: 20403364) vol. 16 issue. 47

研究助成金:

  • Japan Society for the Promotion of Science JP23K04844

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5110

公開URL: https://doi.org/10.1039/d4nr04011b

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更新時刻: 2025-11-04 08:30:10 +0900

MDRでの公開時刻: 2025-11-02 08:22:11 +0900

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