説明:
(abstract)A racemic mixture of N-Fmoc-protected phenylalanine or tryptophan was found to spontaneously afford a gel enriched in either L- or D-form of their enantiomers stochastically. Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the observed phenomenon.
権利情報:
キーワード: Chiral Symmetry Breaking, Gel, Secondary Nucleation
刊行年月日: 2024-11-01
出版者: Royal Society of Chemistry (RSC)
掲載誌:
研究助成金:
原稿種別: 著者最終稿 (Accepted manuscript)
MDR DOI: https://doi.org/10.48505/nims.5110
公開URL: https://doi.org/10.1039/d4nr04011b
関連資料:
その他の識別子:
連絡先:
更新時刻: 2025-11-04 08:30:10 +0900
MDRでの公開時刻: 2025-11-02 08:22:11 +0900
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MS NR-COM-09-2024-004011 R1.pdf
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サイズ | 874KB | 詳細 |