Journal article Tetracene Inclusion in Boron Nitride Nanotubes for Photoluminescence Property Modulation Based on Aggregated State Control in Their Nanocavity
Hayato Saeki (author) (Search by this author)
ORCID https://orcid.org/0000-0001-9072-8414 (unauthenticated)
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Takumi Ehara (author) (Search by this author)
ORCID https://orcid.org/0009-0002-2169-8236 (unauthenticated)
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Kiyoshi Miyata (author) (Search by this author)
ORCID https://orcid.org/0000-0001-6748-1337 (unauthenticated)
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Toshikazu Ono (author) (Search by this author)
ORCID https://orcid.org/0000-0001-5427-8540 (unauthenticated)
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Satoru Emoto (author) (Search by this author)
;
Hiroki Ago (author) (Search by this author)
ORCID https://orcid.org/0000-0003-0908-5883 (unauthenticated)
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Aki Masaoka (author) (Search by this author)
;
Yoichi Sasaki (author) (Search by this author)
ORCID https://orcid.org/0000-0002-0619-7970 (unauthenticated)
ORCID ; ORCID SAMURAI ; ORCID SAMURAI ;
Tsuyohiko Fujigaya (author) (Search by this author)
ORCID https://orcid.org/0000-0003-3563-8234 (unauthenticated)
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Tomohiro Shiraki (author) (Search by this author)
ORCID https://orcid.org/0000-0002-6604-9662 (unauthenticated)
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Citation
Hayato Saeki, Takumi Ehara, Kiyoshi Miyata, Toshikazu Ono, Satoru Emoto, Hiroki Ago, Aki Masaoka, Yoichi Sasaki, Koji Harano, Koji Kimoto, Tsuyohiko Fujigaya, Tomohiro Shiraki. Tetracene Inclusion in Boron Nitride Nanotubes for Photoluminescence Property Modulation Based on Aggregated State Control in Their Nanocavity. The Journal of Physical Chemistry Letters. 2025, 16 (30), 7738-7743. https://doi.org/10.1021/acs.jpclett.5c01618

Description:

(abstract)

Boron nitride nanotubes (BNNTs) are used for the self-assembly of tetracene (Tc) molecules without chemical modification in their one-dimensional nanocavities. The Tc aggregated state can be changed depending on the encapsulated Tc amount that is controlled by the sublimation condition of Tc molecules for the complexation (Tc@BNNTs). As a result, the photophysical processes including singlet fission in the Tc assemblies are varied, which enables the emission mode switching of the aggregation-based fluorescence and the excimer emission for Tc@BNNTs. Consequently, the host–guest complexation using BNNTs allows not only the fabrication and evaluation of optically functionalized molecular assemblies in the nanocavity but also the modulation of their photophysical processes, by which the emission colors of Tc@BNNTs are also tuned.

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  • In Copyright

    This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry Letters, copyright © 2025 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpclett.5c01618.

Keyword: photoluminescence, transmission electron microscopy, host-guest chemistry, boron nitride nanotubes

Date published: 2025-07-31

Publisher: American Chemical Society (ACS)

Journal:

  • The Journal of Physical Chemistry Letters (ISSN: 19487185) vol. 16 issue. 30 p. 7738-7743

Funding:

  • Ministry of Education, Culture, Sports, Science and Technology JPMXP1222KU1007
  • Japan Association for Chemical Innovation
  • Toyota Physical and Chemical Research Institute
  • Core Research for Evolutional Science and Technology JPMJCR20B1
  • Kyushu University
  • ACT-X JPMJAX24D8
  • Japan Society for the Promotion of Science JP21H05232
  • Japan Society for the Promotion of Science JP21H05233
  • Japan Society for the Promotion of Science JP22H01910
  • Japan Society for the Promotion of Science JP22H02159
  • Japan Society for the Promotion of Science JP23H03833
  • Japan Society for the Promotion of Science JP23H04874
  • Japan Society for the Promotion of Science JP23K17863
  • Japan Society for the Promotion of Science JP23K23178
  • Japan Society for the Promotion of Science JP23K23427
  • Japan Society for the Promotion of Science JP24H00407
  • Japan Society for the Promotion of Science JP24K01471
  • Japan Society for the Promotion of Science JP24K01515
  • Japan Society for the Promotion of Science JP24K17745
  • Support for Pioneering Research Initiated by the Next Generation JPMJSP2136

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5623

First published URL: https://doi.org/10.1021/acs.jpclett.5c01618

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Updated at: 2025-08-04 08:57:45 +0900

Published on MDR: 2026-07-24 08:28:17 +0900

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