Takumi Miura
;
Takashi Kitao
;
Keigo E. Yamada
;
Yee Seng Chan
;
Hironobu Hayashi
(National Institute for Materials Science)
;
Hiroko Yamada
;
Takashi Uemura
Collection
Citation
Description:
(abstract)Heptacene was synthesized within a MOF through in situ photochemical conversion of the precursor molecule. This approach accelerated the transformation reaction and suppressed the undesirable side reactions of heptacene via geometrical constraints. The bulk production of isolated heptacene molecules enabled the exploration of single-molecule properties, revealing the elusive electronic ground state of pristine heptacene.
Rights:
Keyword: acenes, host − guest systems, metal-organic frameworks, microporous materials, optoelectronic properties
Date published: 2025-07-11
Publisher: Wiley
Journal:
- Chemistry – A European Journal (ISSN: 15213765) vol. 31 issue. 39 e202501787
Funding:
- Core Research for Evolutional Science and Technology JPMJCR20T3
- Precursory Research for Embryonic Science and Technology JPMJPR21A7
- Ogasawara Foundation for the Promotion of Science and Engineering
- Japan Society for the Promotion of Science JP23KJ0539
- Okazaki National Research Institutes 24‐IMS‐C324
Manuscript type: Publisher's version (Version of record)
MDR DOI:
First published URL: https://doi.org/10.1002/chem.202501787
Related item:
Other identifier(s):
Contact agent:
Updated at: 2025-08-25 12:30:32 +0900
Published on MDR: 2025-08-25 12:19:24 +0900
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