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説明:

Heptacene was synthesized within a MOF through in situ photochemical conversion of the precursor molecule. This approach accelerated the transformation reaction and suppressed the undesirable side reactions of heptacene via geometrical constraints. The bulk production of isolated heptacene molecules enabled the exploration of single-molecule properties, revealing the elusive electronic ground state of pristine heptacene.

権利情報:

• Creative Commons BY-NC Attribution-NonCommercial 4.0 International
  

キーワード: acenes, host − guest systems, metal-organic frameworks, microporous materials, optoelectronic properties

刊行年月日: 2025-07-11

出版者: Wiley

掲載誌:

• Chemistry – A European Journal (ISSN: 15213765) vol. 31 issue. 39 e202501787

研究助成金:

• Core Research for Evolutional Science and Technology JPMJCR20T3
• Precursory Research for Embryonic Science and Technology JPMJPR21A7
• Ogasawara Foundation for the Promotion of Science and Engineering
• Japan Society for the Promotion of Science JP23KJ0539
• Okazaki National Research Institutes 24‐IMS‐C324

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1002/chem.202501787

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更新時刻: 2025-08-25 12:30:32 +0900

MDRでの公開時刻: 2025-08-25 12:19:24 +0900