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Nitridation behavior in Eu-ion doped glass has been investigated using the glass prepared by a sol-gel method. / Euイオンをドープした酸窒化ガラス粉末を作製し、評価することでその窒化過程の検討を行った。

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  © 2026 The Ceramic Society of Japan

  Abstract

  Europium-doped oxynitride glass powder (Sr–Si–Al–O–N) was synthesized by a sol–gel method followed by ammonolysis to investigate the effect of the ammonolysis conditions on the structure and properties of the glass powder. In particular, the effect of the ammonia gas flow rate during nitridation was studied. The effective nitrogen concentration (Neff) in the obtained powder, analyzed by X-ray fluorescence, increased with an increase in the flow rate, and the results of X-ray photoemission, nuclear magnetic resonance, and Fourier transform infrared (FT-IR) spectroscopy measurements indicated that the population of Si–N bonds increased with an increase in Neff. However, the presence of hydrogen-terminated structures, such as –NHn, in the powder with high Neff was confirmed by FT-IR measurements. The presence of hydrogen-terminated structures, such as –Si–NHn, and the thermal stability of these hydrogen-related structures were further investigated by thermal analyses, including thermal desorption measurements, which suggested that hydrogen-terminated structures can be easily formed during the nitridation of the gel and that the formation of hydrogen-terminated structures inhibits the polymerization of the glass structures.
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Keyword: Oxynitride glass,, Nitridation, Ammonolysis, Sol–gel method, Europium, Luminescence

Date published: 2026-03-01

Publisher: Ceramic Society of Japan

Journal:

• Journal of the Ceramic Society of Japan (ISSN: 13486535) vol. 134 issue. 3 p. 87-97 25148

Funding:

• MEXT, Japan JPMXP0112101001 ( the Tokodai Institute for Elemental Strategies)
• MEXT, Japan JPMXP1122683430 (the Data-Driven Materials Research Institute for Electronics)
• MEXT, Japan JPMXP1225NM5319 ( ARIM program)
• MEXT, Japan JPMXP1223NM5260 ( ARIM program)

Manuscript type: Publisher's version (Version of record)

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First published URL: https://doi.org/10.2109/jcersj2.25148

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Updated at: 2026-04-02 09:43:38 +0900

Published on MDR: 2026-04-02 12:25:45 +0900