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Silicon oxide (SiOx) is heralded as the forefront anode material for high‐energy density lithium‐ion batteries, owing to its exceptional specific capacity. Nevertheless, the traditional combination of polyacrylic acid binder and acetylene black conductive carbon continues to struggle with the immense stress induced by the repetitive volume expansion and contraction processes. Here we report a high ionic conductivity, sulfonyl fluoro‐containing binder for SiOx anode via free radical copolymerization reaction between perfluoro (4-methyl‐3,6‐dioxaoct‐7‐ene) sulfonyl fluoride and acrylic acid. The electrode fabrication process incorporated
amino‐functionalized carbon nanotubes (CNT‐NH2) as the conductive agent. A three‐dimensional conductive network structure is constructed through physical and chemical double cross‐linking interactions between the ‐COOH and ‐SO2F functional groups of PAF0.1 binder, the ‐NH2 groups of CNT‐NH2, and the ‐OH groups on the surface of SiOx, including hydrogen bonds and covalent bonds. In addition, the binder induces the formation of a solid electrolyte interphase (SEI) rich in inorganic components such as Li2O, Li2SO3, Li2CO3, and LiF. Benefiting from the synergistic effects of the physically and chemically double cross‐linked three‐dimensional conductive network constructed by the PAF0.1 binder and CNT‐NH2, coupled with the rich‐inorganic SEI, the SiOx anode delivers exceptional rate performance, cycle stability, and lithium‐ion diffusion dynamics.

Rights:

• Creative Commons BY Attribution 4.0 International
  

Keyword: Lithium‐ion batteries, Solid electrolyte interphase (SEI), Silicon oxide anode

Date published: 2024-08-22

Publisher: Wiley

Journal:

• Carbon Neutralization (ISSN: 27693333) vol. 3 issue. 5 p. 857-872

Funding:

• National Natural Science Foundation of China 22379166
• Natural Science Foundation for Distinguished Young Scholars of Hunan Province 2022JJ10089
• Key Research and Development Program of Hunan Province 2023GK2015
• Central South University Innovation‐ Driven Research Programme 2023CXQD034

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1002/cnl2.158

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Updated at: 2024-10-25 16:30:37 +0900

Published on MDR: 2024-10-25 16:30:37 +0900