Article Guest-Responsive Near-Infrared-Luminescent Metal–Organic Cage Organized by Porphyrin Dyes and Yb(III) Complexes

Shota Hosoya ; Sunao Shoji ORCID ; Takayuki Nakanishi SAMURAI ORCID ; Masato Kobayashi ORCID ; Mengfei Wang ; Koji Fushimi ; Tetsuya Taketsugu ORCID ; Yuichi Kitagawa ORCID ; Yasuchika Hasegawa ORCID

manuscript.pdf
Download file (1.28 MB)
Download as zip (1.25 MB)
Collection

Citation
Shota Hosoya, Sunao Shoji, Takayuki Nakanishi, Masato Kobayashi, Mengfei Wang, Koji Fushimi, Tetsuya Taketsugu, Yuichi Kitagawa, Yasuchika Hasegawa. Guest-Responsive Near-Infrared-Luminescent Metal–Organic Cage Organized by Porphyrin Dyes and Yb(III) Complexes. Inorganic Chemistry. 2024, 63 (22), 10108-10113. https://doi.org/10.1021/acs.inorgchem.4c01348

Description:

(abstract)

Metal–organic cages (MOCs) with luminophores have significant advantages for the facile detection of specific molecules based on turn-on or turn-off luminescence changes induced by host–guest　complexation. One important challenge is the development of turn-on-type near-infrared (NIR)-luminescent MOCs. In this study, we synthesized a novel MOC consisting of two porphyrin dyes linked by four Yb(III)　complexes, which exhibit bimodal red and NIR fluorescence signals upon photoexcitation of the porphyrin π system. Single-crystal X-ray structural analysis and computational molecular modeling revealed that planar aromatic perfluorocarbons were intercalated into the MOC. The tight packing between the MOC and guests enhanced the NIR fluorescence of Yb(III) by suppressing energy transfer from the photoexcited porphyrin to　oxygen molecules. Guest-responsive turn-on NIR fluorescence changes in an MOC were successfully demonstrated.

Rights:

  • In Copyright

    This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.4c01348

Keyword: Porphyrin, Luminescence

Date published: 2024-06-03

Publisher: American Chemical Society (ACS)

Journal:

  • Inorganic Chemistry (ISSN: 00201669) vol. 63 issue. 22 p. 10108-10113

Funding:

  • Hokkaido University
  • Ministry of Education, Culture, Sports, Science and Technology
  • Sumitomo Foundation
  • Japan Society for the Promotion of Science JP21K18969
  • Japan Society for the Promotion of Science JP22H02152
  • Japan Society for the Promotion of Science JP22H04516
  • Japan Society for the Promotion of Science JP23K17925
  • National Institute for Materials Science
  • Japan Society for the Promotion of Science JP20H02748
  • Japan Society for the Promotion of Science JP22K14741

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4835

First published URL: https://doi.org/10.1021/acs.inorgchem.4c01348

Related item:

Other identifier(s):

Contact agent:

Updated at: 2025-05-21 08:30:16 +0900

Published on MDR: 2025-05-21 08:28:20 +0900

Filename Size
Filename manuscript.pdf (Thumbnail)
application/pdf 		Size 1.28 MB Detail