Formation of hierarchical supramolecular microstructures from 6-
                    <i>O</i>
                    -alkylated α-cyclodextrin and their application to the selective extraction of long-chain unsaturated fatty acid esters

Haruya Ishida; Shuhei Miyakawa; Hajime Shigemitsu; Kaori Fukuzawa; Toshiyuki Kida

doi:10.1039/d6ra04383f

ジャーナル論文 Formation of hierarchical supramolecular microstructures from 6- O -alkylated α-cyclodextrin and their application to the selective extraction of long-chain unsaturated fatty acid esters

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Haruya Ishida, Shuhei Miyakawa, Hajime Shigemitsu, Kaori Fukuzawa, Toshiyuki Kida. Formation of hierarchical supramolecular microstructures from 6- O -alkylated α-cyclodextrin and their application to the selective extraction of long-chain unsaturated fatty acid esters. RSC Advances. 2026, 16 (36), 38221-38227. https://doi.org/10.1039/d6ra04383f

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(abstract)

We successfully fabricated rhombic plate-like microstructures composed of layered assemblies ofhead-tohead supramolecular dimers of 6-O-methylated and 6-O-ethylated a-cyclodextrins (6-Me-a-CD and 6Et-a-CD, respectively). 6-Me-a-CD selectively extracted methyl elaidate (trans) over methyl oleate (cis) in methanol via microstructure formation driven by inclusion complexation between the 6-Me-a-CD dimer and fatty acid esters, whereas 6-Et-a-CD exhibited the opposite selectivity. These results demonstrate that subtle modulation of the alkyl chain length at the 6-O position of a-CD enables reversal of cis/trans selectivity in supramolecular extraction behavior. The origin of this selectivity was further elucidated by theoretical calculations based on density functional theory (DFT) and fragment molecular orbital (FMO) interaction energy analysis.

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