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Fabrication of two-dimensional (2D) transition-metal oxides has gained considerable attention due to their unique crystal structures and physical properties distinct from their bulk counterparts. Intercalation of foreign elements into the graphene/SiC(0001) interface is a possible approach for achieving this, as it enables the confinement and arrangement of atoms within the 2D interface. However, while various 2D metals and their compounds have been synthesized at the graphene/SiC interface, the fabrication of 2D transition-metal compounds remains challenging. This difficulty arises from the high reactivity of transition metals such as Fe, Co, and Ni, which readily form carbides and silicides with the host material. In this work, the fabrication of a 2D iron oxide at the graphene/SiC interface is demonstrated through the simultaneous intercalation of Fe and O. Direct observation using atomic-resolution electron microscopy revealed that the crystalline 2D iron oxide is encapsulated by graphene and forms a sharp interface with the SiC substrate. Structural analysis and Mössbauer spectroscopy suggest that the 2D iron oxide exhibits a wüstite-like structure. These findings provide another strategy for synthesizing 2D transition-metal oxides, opening new avenues for the advancement of 2D magnetic materials.

権利情報:

• Creative Commons BY-NC Attribution-NonCommercial 4.0 International
  

キーワード: 2D materials, Graphene, SiC, Transmission Electron Microscopy, Intercalation

刊行年月日: 2026-03-14

出版者: Wiley

掲載誌:

• Small Methods (ISSN: 23669608) vol. 10 issue. 8 e01889

研究助成金:

• Japan Society for the Promotion of Science JP22KJ1535
• Japan Society for the Promotion of Science JP25K17917
• Japan Society for the Promotion of Science JP21K14500

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1002/smtd.202501889

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更新時刻: 2026-04-27 08:49:30 +0900

MDRでの公開時刻: 2026-04-27 10:27:48 +0900