Sacrificial carbon fiber-nickel hydroxide core-shell particles for nickel oxide diffusion from pore surfaces to grain interfaces in zirconia

Shingo Machida; Yuki Sada; Daiki Takeda; Shintaro Matsushita; Daisaku Yokoe; Kentaro Uesugi; Akihisa Takeuchi; Gaku Okuma; Tetsuya Yamada

doi:10.1039/D5CE01187F

論文 Sacrificial carbon fiber-nickel hydroxide core-shell particles for nickel oxide diffusion from pore surfaces to grain interfaces in zirconia

Shingo Machida (JFCC) ; Yuki Sada (Japan Synchrotron Radiation Research Institute (JASRI)) ; Daiki Takeda (Industrial Research Institute of Ishikawa) ; Shintaro Matsushita (Institute of Science Tokyo) ; Daisaku Yokoe (JFCC) ; Kentaro Uesugi (Japan Synchrotron Radiation Research Institute (JASRI)) ; Akihisa Takeuchi (Japan Synchrotron Radiation Research Institute (JASRI)) ; Gaku Okuma (Research Center for Structural Materials/Materials Manufacturing Field/Ceramic Matrix Composites Group, National Institute for Materials Science) ; Tetsuya Yamada (Institute of Science Tokyo)

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Shingo Machida, Yuki Sada, Daiki Takeda, Shintaro Matsushita, Daisaku Yokoe, Kentaro Uesugi, Akihisa Takeuchi, Gaku Okuma, Tetsuya Yamada. Sacrificial carbon fiber-nickel hydroxide core-shell particles for nickel oxide diffusion from pore surfaces to grain interfaces in zirconia . CRYSTENGCOMM. 2026, 28 (11), 1828-1836. https://doi.org/10.1039/D5CE01187F

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(abstract)

The sacrificial use of core–shell particles offers a versatile strategy for generating porous structures while increasing oxide–oxide interfaces within porous materials through diffusion of oxide species from pore surfaces to grain interfaces. In this study, carbon fiber (CF)–nickel hydroxide core–shell particles were combined with zirconia and calcined to produce porous zirconia sintered bodies containing nickel oxide at zirconia grain boundaries. Core–shell particles bearing vertically aligned platy nickel hydroxide on CF surfaces are prepared by a hydrothermal reaction. Upon calcination with zirconia at 1300°C for 12 h, the CF cores were removed by combustion, and the nickel hydroxide shells were converted into tubular nickel oxide hollow particles, whose interiors acted as pores within the zirconia matrix. Complementary analyses—including X-ray diffraction, electron microscopy, elemental mapping, and multiscale synchrotron X-ray computed tomography—revealed that nickel oxide is present in minute amounts, forming thin layers at zirconia grain boundaries and on portions of the pore surfaces. Compared with zirconia sintered without the core–shell particles, the zirconia-core-shell particle system suggests that interfacial diffusion of nickel oxide suppresses zirconia grain growth. These results demonstrate that both the CF core and the nickel hydroxide shell act sacrificially to create interconnected pores while designing additional oxide–oxide interfaces at pore surfaces, thereby generating an increased three-phase oxide–oxide–pore interfacial environment within the sintered bodies.

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