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A redox-neutral Fe-electrocatalytic deoxygenative Giese reaction is reported.
Hydroxyl groups are among the most abundant functional groups; therefore, the development of efficient methods for their transformation is of significant importance in medicinal and process chemistry. Here, we present a redox-neutral Giese reaction that proceeds via anodic oxidation to generate phosphonium ions, combined with cathodic reduction to furnish low-valent Fe catalysts. This reaction represents a promising example of a redox-neutral transformation enabled by an Fe catalyst and electrochemistry. The results obtained in this study will facilitate the exploration of a broad range of novel reactions employing this redox cycle in the future.

権利情報:

• Creative Commons BY-NC-ND Attribution-NonCommercial-NoDerivs 4.0 International
  

キーワード: Fe-electrocatalysis, Deoxygenative Giese reaction, Redox-neutral electrochemistry, C–C bond formation, Hydroxyl group functionalization

刊行年月日: 2025-09-26

出版者: Springer Science and Business Media LLC

掲載誌:

• Nature Communications (ISSN: 20411723) vol. 16 issue. 1 8379

研究助成金:

• Research Grants Council, University Grants Committee ECS, HKUST 26302024
• Hong Kong University of Science and Technology Start-up funds (Project No. R9820)

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1038/s41467-025-63515-x

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更新時刻: 2025-12-24 15:09:39 +0900

MDRでの公開時刻: 2025-12-24 16:20:28 +0900