Article Two‐Dimensional Living Supramolecular Polymerization: Improvement in Edge Roughness of Supramolecular Nanosheets by Using a Dummy Monomer

Zhehui Jin SAMURAI ORCID (National Institute for Materials Science) ; Norihiko Sasaki ORCID (National Institute for Materials Science) ; Natsuki Kishida ; Masayuki Takeuchi SAMURAI ORCID (National Institute for Materials Science) ; Yutaka Wakayama SAMURAI ORCID (National Institute for Materials Science) ; Kazunori Sugiyasu SAMURAI ORCID (National Institute for Materials Science)

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Zhehui Jin, Norihiko Sasaki, Natsuki Kishida, Masayuki Takeuchi, Yutaka Wakayama, Kazunori Sugiyasu. Two‐Dimensional Living Supramolecular Polymerization: Improvement in Edge Roughness of Supramolecular Nanosheets by Using a Dummy Monomer. Chemistry – A European Journal. 2023, 29 (65), e202302181. https://doi.org/10.1002/chem.202302181
SAMURAI

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(abstract)

Supramolecular polymers are formed through nucleation (i.e., initiation) and polymerization processes, and kinetic control over the nucleation process has recently led to the realization of living supramolecular polymerization. Changing the viewpoint, herein, we focus on controlling the polymerization process, which we expect to pave the way to further developments in controlled supramolecular polymerization. In our previous study, two-dimensional living supramolecular polymerization was used to produce supramolecular nanosheets with a controlled area; however, these had rough edges. In this study, the growth of the nanosheets was controlled by using a ‘dummy’ monomer to produce supramolecular nanosheets with smoothed edges.

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  • In Copyright

    This is the peer reviewed version of the following article: Z. Jin, N. Sasaki, N. Kishida, M. Takeuchi, Y. Wakayama, K. Sugiyasu, Chem. Eur. J. 2023, 29, e202302181, which has been published in final form at https://doi.org/10.1002/chem.202302181. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

Keyword: supramolecular polymers, two-dimensional polymerization, dummy monomers, edge roughness

Date published: 2023-11-21

Publisher: Wiley

Journal:

  • Chemistry – A European Journal (ISSN: 15213765) vol. 29 issue. 65 e202302181

Funding:

  • Murata Science Foundation
  • Sekisui Chemical
  • Mitsubishi Foundation
  • Ministry of Education, Culture, Sports, Science and Technology JP19K05592
  • Ministry of Education, Culture, Sports, Science and Technology JP22H02134
  • Ministry of Education, Culture, Sports, Science and Technology 20H04682
  • Ministry of Education, Culture, Sports, Science and Technology JP20H05868
  • Ministry of Education, Culture, Sports, Science and Technology JPMXP1122714694
  • Izumi Science and Technology Foundation
  • Iketani Science and Technology Foundation

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4894

First published URL: https://doi.org/10.1002/chem.202302181

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Updated at: 2024-10-25 16:30:41 +0900

Published on MDR: 2024-10-25 16:30:41 +0900

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