Article Microstructure evolution and phase analysis of Sm60Ni40 alloy

G. Vijayaragavan ; D. Prabhu ; M.B. Ponnuchamy ; K.R.S. Preethi Meher ; Ravi Gautam ; Mainak Saha SAMURAI ORCID (Metallurgical and Materials Engineering, Indian Institute of Technology Madras) ; R. Gopalan ; K.G. Pradeep

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G. Vijayaragavan, D. Prabhu, M.B. Ponnuchamy, K.R.S. Preethi Meher, Ravi Gautam, Mainak Saha, R. Gopalan, K.G. Pradeep. Microstructure evolution and phase analysis of Sm60Ni40 alloy. Journal of Magnetism and Magnetic Materials. 2022, 566 (), 170323. https://doi.org/10.1016/j.jmmm.2022.170323

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(abstract)

The paper investigates the microstructure evolution and phase analysis of the Sm60Ni40 alloy. The arc melted sample retained the high temperature stable (>873 K) Sm7Ni3 and Sm3Ni2 phases along with the congruently melting SmNi phase. Annealing the as-cast sample at 903 K for 100 h stabilized the high temperature stable (873 K − 903 K) Sm3Ni2 phase. Rietveld refinement was performed to resolve the crystal structure of Sm3Ni2 phase and it was observed that Sm3Ni2 phase stabilizes in monoclinic crystal structure (space group: C2/m) with a lattice parameter of a = 13.49 Å, b = 3.75 Å, c = 9.68 Å and β = 106.6°. The Curie temperature of the Sm3Ni2 phase was determined to be ∼ 110 K. The high squareness ratio of 82 % along with high coercivity of 3 T indicates that the Sm3Ni2 phase possess spontaneous uniaxial magnetic anisotropy.

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Keyword: Sm-Ni alloy, Annealing, Microstructure, Magnetic property, Crystal structure

Date published: 2022-12-26

Publisher: Elsevier

Journal:

  • Journal of Magnetism and Magnetic Materials (ISSN: 03048853) vol. 566 170323

Funding:

Manuscript type: Author's version (Submitted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4628

First published URL: https://doi.org/10.1016/j.jmmm.2022.170323

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Updated at: 2024-10-29 16:44:05 +0900

Published on MDR: 2024-08-06 12:30:20 +0900

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