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Description:

The dynamic covalent chemistry of molecular disulfides has been studied extensively in solution, but their reactivity when confined to nanospaces has not been investigated, nor has their application to functional nanomaterials been explored. In this study, symmetrical organic disulfides were tethered to the basal planes of synthetic mica by intercalation, confining photo-induced reactions to the interlayer as a result. This approach functionalizes the nanosheets to act as host for photo-induced disulfide-disulfide, disulfide-thiol, and disulfide-ene reactions, providing control and versatility for a wide variety of applications.

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• In Copyright
  

  ©2022 The Chemical Society of Japan

Keyword: Disulfide chemistry, Layered silicates, Photo-reactivity

Date published: 2023-01-15

Publisher: The Chemical Society of Japan

Journal:

• Bulletin of the Chemical Society of Japan (ISSN: 13480634) vol. 96 issue. 1 p. 65-71

Funding:

• JSPS Grant-in-Aid for Young Scientists (KAKENHI) (Understanding the Relationship between Polymer Structure and Creep Deformation/Failure by Multiscale Analysis)
• JSPS Grant-in-Aid for Scientific Research (KAKENHI) (ヒドロキシアルミニウム変質粘土表面における原子・分子レベルのセシウム吸着挙動解析)

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4302

First published URL: https://doi.org/10.1246/bcsj.20220309

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Updated at: 2024-01-05 22:12:44 +0900

Published on MDR: 2023-12-12 13:30:27 +0900