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説明:

The dynamic covalent chemistry of molecular disulfides has been studied extensively in solution, but their reactivity when confined to nanospaces has not been investigated, nor has their application to functional nanomaterials been explored. In this study, symmetrical organic disulfides were tethered to the basal planes of synthetic mica by intercalation, confining photo-induced reactions to the interlayer as a result. This approach functionalizes the nanosheets to act as host for photo-induced disulfide-disulfide, disulfide-thiol, and disulfide-ene reactions, providing control and versatility for a wide variety of applications.

権利情報:

• In Copyright
  

  ©2022 The Chemical Society of Japan

キーワード: Disulfide chemistry, Layered silicates, Photo-reactivity

刊行年月日: 2023-01-15

出版者: The Chemical Society of Japan

掲載誌:

• Bulletin of the Chemical Society of Japan (ISSN: 13480634) vol. 96 issue. 1 p. 65-71

研究助成金:

• JSPS Grant-in-Aid for Young Scientists (KAKENHI) (Understanding the Relationship between Polymer Structure and Creep Deformation/Failure by Multiscale Analysis)
• JSPS Grant-in-Aid for Scientific Research (KAKENHI) (ヒドロキシアルミニウム変質粘土表面における原子・分子レベルのセシウム吸着挙動解析)

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4302

公開URL: https://doi.org/10.1246/bcsj.20220309

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更新時刻: 2024-01-05 22:12:44 +0900

MDRでの公開時刻: 2023-12-12 13:30:27 +0900