山崎 陽菜
;
武田 真理子
;
髙木 優香
;
永田 肇
;
阿部 聡子
;
打越 哲郎
(National Institute for Materials Science)
;
宗像 文男
Description:
(abstract)The effect of self-assembled barium titanate (BT) aggregates in polyvinylidene fluoride (PVDF) matrix on the α‐β phase transition was investigated. The self-assembled BT/PVDF composites were prepared with and without dispersant in the self-assembled process. The addition of dispersants increased the average secondary particle area (S) of the BT particles and promoted the BT/PVDF/BT hetero-interface. FT-IR showed that the α‐β phase transition of the composites enhanced with increasing S. The Cole-Cole plot was estimated the existence of orientation polarization and interface polarization. According to these results, we proposed a BT/PVDF/BT hetero-interface model based on the double Schottky barrier model.
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Keyword: BaTiO3/PVDF, phase transition, hetero-interface, double Shottky, barrier model, aggregates
Date published: 2022-05-15
Publisher: Japan Society of Powder and Powder Metallurgy
Journal:
Funding:
Manuscript type: Publisher's version (Version of record)
MDR DOI:
First published URL: https://doi.org/10.2497/jjspm.69.195
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Updated at: 2024-12-24 13:58:29 +0900
Published on MDR: 2024-12-24 13:58:29 +0900
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