Article High Cathode Loading and Low‐Temperature Operating Garnet‐Based All‐Solid‐State Lithium Batteries – Material/Process/Architecture Optimization and Understanding of Cell Failure

Hirotoshi Yamada ORCID ; Tomoko Ito ; Tatsuya Nakamura ; Raman Bekarevich ORCID ; Kazutaka Mitsuishi SAMURAI ORCID (National Institute for Materials Science) ; Sanoop Palakkathodi Kammampata ; Venkataraman Thangadurai ORCID

Small - 2023 - Yamada - High Cathode Loading and Low‐Temperature Operating Garnet‐Based All‐Solid‐State Lithium Batteries .pdf
Download file (3.67 MB)
Download as zip (3.28 MB)
Collection

Citation
Hirotoshi Yamada, Tomoko Ito, Tatsuya Nakamura, Raman Bekarevich, Kazutaka Mitsuishi, Sanoop Palakkathodi Kammampata, Venkataraman Thangadurai. High Cathode Loading and Low‐Temperature Operating Garnet‐Based All‐Solid‐State Lithium Batteries – Material/Process/Architecture Optimization and Understanding of Cell Failure. Small. 2023, 19 (36), 2301904. https://doi.org/10.1002/smll.202301904
SAMURAI

Description:

(abstract)

All-solid-state lithium batteries (ASSLBs) are prepared using garnet-type solid electrolytes by quick liquid phase sintering (Q-LPS) without applying high pressure during the sintering. The cathode layers are quickly sintered with a heating rate of 50–100 K min−1 and a dwell time of 10 min. The battery performance is dramatically improved by simultaneously optimizing materials, processes, and architectures, and the initial discharge capacity of the cell with a LiCoO2-loading of 8.1 mg reaches 1 mAh cm−2 and 130 mAh g−1 at 25 °C. The all-solid-state cell exhibits capacity at a reduced temperature (10 °C) or a relatively high rate (0.1 C) compared to the previous reports. The Q-LPS would be suitable for large-scale manufacturing of ASSLBs.

Rights:

Keyword: All-solid-state lithium batteries

Date published: 2023-04-28

Publisher: Wiley

Journal:

  • Small (ISSN: 16136810) vol. 19 issue. 36 2301904

Funding:

  • Advanced Low Carbon Technology Research and Development Program
  • Japan Science and Technology Agency JST‐ALCA SPRING
  • Japan Science and Technology Agency JPMJAC1301
  • Natural Sciences and Engineering Research Council of Canada RGPIN‐2021‐02493

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1002/smll.202301904

Related item:

Other identifier(s):

Contact agent:

Updated at: 2024-12-18 08:30:48 +0900

Published on MDR: 2024-12-18 08:30:48 +0900

Filename Size
Filename Small - 2023 - Yamada - High Cathode Loading and Low‐Temperature Operating Garnet‐Based All‐Solid‐State Lithium Batteries .pdf (Thumbnail)
application/pdf 		Size 3.67 MB Detail