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The solid-state cooling/heating technology based on the elastocaloric effect is one of the promising alternatives to vapor compression systems. The large elastocaloric temperature modulation is often generated through the non-linear strain-induced structural transition by applying large strain and/or stress to ferroelastic materials. Recently, an unconventional approach to expand the application possibilities of the elastocaloric effect was demonstrated by processing elastocaloric materials into kirigami structures, which was inspired by the art of paper cutting. By using this approach, only a small stretch of processed conventional plastics can locally provide more efficient performance of elastocaloric temperature modulation than that of ferroelastic materials. To further improve such a unique functionality, it is necessary to find plastic or polymeric materials showing large elastocaloric effects in the linear elastic response regime that can be driven by a MPa-order weak stress application, where the non-linear structural transition is irrelevant. In this work, by means of recently developed measurement technique for the elastocaloric effect based on the lock-in thermography, we found that shape memory polymers (SMPs) show prominent performance of the elastocaloric temperature modulation that is larger than conventional plastics. SMPs enable the control of the crystallinity by changing the cross-linking agents, melting temperature by changing the degree of polymerization, and orientation of the polymer chain segment by the shape memory effect. By utilizing the unique properties of SMPs, we manipulated their elastocaloric performance. The experimental results reported here will highlight the potential of smart polymers for flexible and durable elastocaloric applications.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: Elastocaloric effect, Shape memory polymer

刊行年月日: 2023-07-01

出版者: IOP Publishing

掲載誌:

• Journal of Physics-Energy (ISSN: 25157655) vol. 5 issue. 3 p. 34011-34011

研究助成金:

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.1088/2515-7655/ace7f3

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更新時刻: 2024-01-05 22:12:33 +0900

MDRでの公開時刻: 2023-10-17 13:30:16 +0900