Article Light-Induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-Temperature H2 Production from Methanol and Water

Shunqin Luo ORCID (National Institute for Materials Science) ; Hui Song (National Institute for Materials Science) ; Fumihiko Ichihara SAMURAI ORCID (National Institute for Materials Science) ; Mitsutake Oshikiri SAMURAI ORCID (National Institute for Materials Science) ; Wenning Lu ; Dai-Ming Tang SAMURAI ORCID (National Institute for Materials Science) ; Sijie Li ; Yunxiang Li ; Yifan Li ORCID (National Institute for Materials Science) ; Philo Davin ORCID (National Institute for Materials Science) ; Tetsuya Kako SAMURAI ORCID (National Institute for Materials Science) ; Huiwen Lin ORCID (National Institute for Materials Science) ; Jinhua Ye SAMURAI ORCID (National Institute for Materials Science)

Light-induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-temperature H2 Production from Methanol and Water.pdf
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Shunqin Luo, Hui Song, Fumihiko Ichihara, Mitsutake Oshikiri, Wenning Lu, Dai-Ming Tang, Sijie Li, Yunxiang Li, Yifan Li, Philo Davin, Tetsuya Kako, Huiwen Lin, Jinhua Ye. Light-Induced Dynamic Restructuring of Cu Active Sites on TiO2 for Low-Temperature H2 Production from Methanol and Water. Journal of the American Chemical Society. 2023, 145 (37), 20530-20538. https://doi.org/10.1021/jacs.3c06688
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(abstract)

メタノールからCu/TiO2触媒を利用して、水素を生成させる反応を行った。低温で反応を実施すると、銅が酸化されて、すぐに失活するが、光を照射しながら、反応を実施すると、銅の酸化を抑制でき、活性をキープすることができることが明らかとなった。

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  • In Copyright

    This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.3c06688

Keyword: hydrogen, methanol, Cu, photothermal

Date published: 2023-09-20

Publisher: American Chemical Society (ACS)

Journal:

  • Journal of the American Chemical Society (ISSN: 15205126) vol. 145 issue. 37 p. 20530-20538

Funding:

  • Hokkaido University
  • Japan Society for the Promotion of Science JP18H02065
  • Japan Society for the Promotion of Science JP21K04782
  • National Natural Science Foundation of China 42103016
  • World Premier International Research Center Initiative

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4784

First published URL: https://doi.org/10.1021/jacs.3c06688

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Updated at: 2024-09-30 16:30:35 +0900

Published on MDR: 2024-09-30 16:30:35 +0900

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