Article Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C60 and C70 in solution and 1D-alignment of fullerenes in the crystals

Peifeng Mei ORCID ; Hirofumi Morimoto ; Yuta Okada ; Kyohei Matsuo ORCID ; Hironobu Hayashi SAMURAI ORCID ; Akinori Saeki ORCID ; Hiroko Yamada ORCID ; Naoki Aratani ORCID

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Peifeng Mei, Hirofumi Morimoto, Yuta Okada, Kyohei Matsuo, Hironobu Hayashi, Akinori Saeki, Hiroko Yamada, Naoki Aratani. Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C60 and C70 in solution and 1D-alignment of fullerenes in the crystals. RSC Advances. 2023, 13 (47), . https://doi.org/10.1039/d3ra06526j
SAMURAI

Description:

(abstract)

To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexation in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C60@N6 composite have semiconductive properties revealed by photoconductivity measurements.

Description:

(abstract)

To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexation in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C60@N6 composite have semiconductive properties revealed by photoconductivity measurements.

Description:

(abstract)

To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexation in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C60@N6 composite have semiconductive properties revealed by photoconductivity measurements.

Description:

(abstract)

To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexation in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C60@N6 composite have semiconductive properties revealed by photoconductivity measurements.

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Keyword: macrocycle, fullerene, host-guest, charge tansfer

Date published: 2023-11-14

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Journal:

  • RSC Advances (ISSN: 20462069) vol. 13 issue. 47

Funding:

  • Japan Society for the Promotion of Science JP20H00379
  • Japan Society for the Promotion of Science JP20H02816
  • Japan Society for the Promotion of Science JP20H05833
  • Japan Society for the Promotion of Science JP20H05836
  • Japan Society for the Promotion of Science JP22K05255
  • Japan Society for the Promotion of Science JP22K19067
  • Japan Society for the Promotion of Science JP23H01787
  • Japan Science and Technology Corporation JPMJPR21AC
  • Precursory Research for Embryonic Science and Technology

Manuscript type: Publisher's version (Version of record)

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First published URL: https://doi.org/10.1039/d3ra06526j

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Updated at: 2024-05-16 16:32:55 +0900

Published on MDR: 2023-12-22 16:30:19 +0900

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