Subarna Maity
;
Toshiki Komagata
;
Shinjiro Takano
;
Shinya Masuda
;
Jun Kikkawa
;
Koji Kimoto
;
Koji Harano
;
Tatsuya Tsukuda
説明:
(abstract)Gold ultrathin nanorods (Au UNRs) are anisotropic nanostructures constructed by attaching gold nanoclusters in one dimension. Au UNRs exhibit localized surface plasmon resonance (LSPR) only in the longitudinal direction because their diameter is smaller than the Fermi wavelength of an electron (<2 nm). In this study, we found that the LSPR wavelength of oleylamine-stabilized Au UNRs is blue shifted simply by mixing with Ag(I). High-resolution elemental mapping and X-ray photoemission spectroscopy of the resulting UNRs indicate that an Ag monoatomic layer is formed on the Au UNR surface by the antigalvanic reduction of Ag(I). This process allowed us to synthesize a series of Au@Ag core-shell UNRs with LSPR wavelengths in the range of 1.2–2.0 μm.
権利情報:
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.nanolett.4c03159
キーワード: Gold Ultrathin Nanorod, Localized Surface Plasmon Resonance, Au@Ag Core-Shell Structure, Antigalvanic Reaction
刊行年月日: 2024-10-23
出版者: American Chemical Society (ACS)
掲載誌:
研究助成金:
原稿種別: 著者最終稿 (Accepted manuscript)
MDR DOI: https://doi.org/10.48505/nims.4892
公開URL: https://doi.org/10.1021/acs.nanolett.4c03159
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更新時刻: 2025-09-26 08:30:35 +0900
MDRでの公開時刻: 2025-09-26 08:18:15 +0900