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Description:

A syngas was generated at a near-unity H2/CO ratio independent of the reactant gas composition over Rh-loaded strontium titanate in the photo-induced dry reforming of methane. Moreover, light irradiation inhibited side reactions, such as the reverse water gas shift reaction and the precipitation of the solid-state carbon. These results were not explained by thermodynamic equilibrium, but were presumably owing to the unique effect of the photogenerated electron–hole pairs.

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• In Copyright
  

Keyword: Photo-induced catalysis, Dry reforming of methane

Date published: 2024-08-22

Publisher: Royal Society of Chemistry (RSC)

Journal:

• Chemical Communications (ISSN: 13597345) vol. 60 issue. 75 p. 10406-10409

Funding:

• Japan Society for the Promotion of Science 23H02042 (KAKENHI)
• Japan Society for the Promotion of Science 23K17953 (KAKENHI)
• Japan Society for the Promotion of Science 23K26735 (KAKENHI)
• Acquisition, Technology & Logistics Agency JPJ004596 (Innovative Science and Technology Initiative for Security)

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5171

First published URL: https://doi.org/10.1039/d4cc03088e

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Updated at: 2025-08-22 08:30:19 +0900

Published on MDR: 2025-08-22 08:17:05 +0900