論文 Surface Passivation of Sn-Based Wide Band Gap Perovskite Solar Cells Using Functional Molecules

Dhruba B. Khadka SAMURAI ORCID (National Institute for Materials Science) ; Masatoshi Yanagida SAMURAI ORCID (National Institute for Materials Science) ; Roji Sahara SAMURAI ORCID (National Institute for Materials Science) ; Yasuhiro Shirai SAMURAI ORCID (National Institute for Materials Science)

コレクション

引用
Dhruba B. Khadka, Masatoshi Yanagida, Roji Sahara, Yasuhiro Shirai. Surface Passivation of Sn-Based Wide Band Gap Perovskite Solar Cells Using Functional Molecules. Conference Record of the IEEE Photovoltaic Specialists Conference. 2025, 1 (), 680-682. https://doi.org/10.1109/pvsc59419.2025.11133091

説明:

(abstract)

Surface passivation with multifunctional molecules is a powerful approach to enhancing the performance and stability of perovskite solar cells (PSCs). This study reports the fabrication of wide-bandgap tin-based perovskite solar cells (WB-Sn-PSCs) with a bandgap of 1.68 eV, achieving a power conversion efficiency of 11.14%. Molecular surface passivation using 4-Fluorobenzohydrazide (F-BHZ) significantly improves device performance and stability by engineering both the surface and bulk properties of the WB-Sn-HP film. F-BHZ treatment strengthens electrostatic potential and molecular interactions with functional groups, mitigating surface defects and suppressing Sn2⁺ oxidation, as confirmed by theoretical calculations. This work highlights the potential of advanced chemical engineering strategies to optimize non-toxic, lead-free perovskite solar cells, advancing their competitiveness as environmentally friendly photovoltaic solutions.

権利情報:

  • In Copyright

    © 2025 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.

キーワード: Perovskite Solar Cells, Sn-perovskite, Surface Passivation, Wide Band Gap Perovskite

刊行年月日: 2025-06-08

出版者: IEEE

掲載誌:

  • Conference Record of the IEEE Photovoltaic Specialists Conference (ISSN: 01608371) vol. 1 p. 680-682

研究助成金:

  • Hitachi

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.6224

公開URL: https://doi.org/10.1109/pvsc59419.2025.11133091

関連資料:

その他の識別子:

連絡先:

更新時刻: 2026-03-19 14:27:08 +0900

MDRでの公開時刻: 2026-03-19 13:36:20 +0900

ファイル名 サイズ
ファイル名 PVSC-53_WB-Sn-PSCs.pdf (サムネイル)
application/pdf
サイズ 544KB 詳細