Dhruba B. Khadka
(National Institute for Materials Science)
;
Masatoshi Yanagida
(National Institute for Materials Science)
;
Roji Sahara
(National Institute for Materials Science)
;
Yasuhiro Shirai
(National Institute for Materials Science)
説明:
(abstract)Surface passivation with multifunctional molecules is a powerful approach to enhancing the performance and stability of perovskite solar cells (PSCs). This study reports the fabrication of wide-bandgap tin-based perovskite solar cells (WB-Sn-PSCs) with a bandgap of 1.68 eV, achieving a power conversion efficiency of 11.14%. Molecular surface passivation using 4-Fluorobenzohydrazide (F-BHZ) significantly improves device performance and stability by engineering both the surface and bulk properties of the WB-Sn-HP film. F-BHZ treatment strengthens electrostatic potential and molecular interactions with functional groups, mitigating surface defects and suppressing Sn2⁺ oxidation, as confirmed by theoretical calculations. This work highlights the potential of advanced chemical engineering strategies to optimize non-toxic, lead-free perovskite solar cells, advancing their competitiveness as environmentally friendly photovoltaic solutions.
権利情報:
© 2025 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.
キーワード: Perovskite Solar Cells, Sn-perovskite, Surface Passivation, Wide Band Gap Perovskite
刊行年月日: 2025-06-08
出版者: IEEE
掲載誌:
研究助成金:
原稿種別: 著者最終稿 (Accepted manuscript)
MDR DOI: https://doi.org/10.48505/nims.6224
公開URL: https://doi.org/10.1109/pvsc59419.2025.11133091
関連資料:
その他の識別子:
連絡先:
更新時刻: 2026-03-19 14:27:08 +0900
MDRでの公開時刻: 2026-03-19 13:36:20 +0900
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PVSC-53_WB-Sn-PSCs.pdf
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