論文 Design of all-inorganic Sr5(PO4)3Cl: Eu2+ phosphor-in-glass for next generation violet-chips-excited sunlight-like healthy lighting

Ziyu He ; Guoqiang Yin ; Suiyuan Dong ; Guoying Zhao ; Yufeng Liu ; Bo Li ; Hong-Tao Sun SAMURAI ORCID (National Institute for Materials Science) ; Jingshan Hou ; Feng Wang ; Yongzheng Fang

コレクション

引用
Ziyu He, Guoqiang Yin, Suiyuan Dong, Guoying Zhao, Yufeng Liu, Bo Li, Hong-Tao Sun, Jingshan Hou, Feng Wang, Yongzheng Fang. Design of all-inorganic Sr5(PO4)3Cl: Eu2+ phosphor-in-glass for next generation violet-chips-excited sunlight-like healthy lighting. CERAMICS INTERNATIONAL. 2025, 51 (18), 26431-26442. https://doi.org/10.1016/j.ceramint.2025.03.324

説明:

(abstract)

To call for green and low-carbon lighting development strategy, sunlight-like health lighting has become the next generation of light-emitting diode (LED) trends. The conventional LEDs are deficient in the violet part and contain high-radiation blue light which is harmful to human eyes. The traditional organic phosphor and chip packaging mode leads to poor heat dissipation. Therefore, it cannot meet the human demand for high-quality, healthy lighting. In this study, a series of violet-excitable blue Sr5(PO4)3Cl: Eu2+ (SPOC) phosphor-in-glass (PiG) films were prepared. The PiG film can not only compensate for the violet-yellow gap in the spectral component but also have excellent luminescence performance and reliability. Significantly, the lower co-sintering temperature (335 ℃) allows it to maintain 89% of the initial phosphor quantum efficiency. Relative to the initial state, PiG (Ea = 0.143 eV) at the optimal sintering temperature maintains a 34% higher resistance to thermal quenching than phosphor-in-silicon (PiS) at 175°C. This blue PiG-prepared color converter was remotely packaged with a violet chip to achieve a sunlight-like LED with a color rendering index of 96.3 and 100% color saturation. This research offers great potential for the development of next-generation sunlight-like health lighting.

権利情報:

キーワード: luminescent materials

刊行年月日: 2025-03-22

出版者: Elsevier BV

掲載誌:

  • CERAMICS INTERNATIONAL (ISSN: 02728842) vol. 51 issue. 18 p. 26431-26442

研究助成金:

原稿種別: 査読前原稿 (Author's original)

MDR DOI: https://doi.org/10.48505/nims.5567

公開URL: https://doi.org/10.1016/j.ceramint.2025.03.324

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更新時刻: 2025-07-09 12:30:31 +0900

MDRでの公開時刻: 2025-07-09 12:17:18 +0900

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