論文 Fine-Tuning of the Sequential Self-Assembly of Entangled Polyhedra by Exploiting the Side-Chain Effect

Yuya Domoto (Gunma University) ; Ren Nakabayashi (Gunma University) ; Tasuki Tsurumi (Gunma University) ; Kidai Yamamoto (University of Tokyo) ; Hironobu Hayashi SAMURAI ORCID (Center for Basic Research on Materials/Advanced Materials Characterization Field/Nanoprobe Group, National Institute for Materials Science) ; Yosuke Nakamura (Gunma University) ; Makoto Fujita (University of Tokyo)

コレクション

引用
Yuya Domoto, Ren Nakabayashi, Tasuki Tsurumi, Kidai Yamamoto, Hironobu Hayashi, Yosuke Nakamura, Makoto Fujita. Fine-Tuning of the Sequential Self-Assembly of Entangled Polyhedra by Exploiting the Side-Chain Effect. CHEMISTRY-AN ASIAN JOURNAL. 2025, 20 (6), . https://doi.org/10.1002/asia.202401378

説明:

(abstract)

側鎖効果を利用した、高度に絡み合ったAg配位多面体の逐次的な自己集合過程の制御を、三脚配位子への直鎖・分岐側鎖の導入により検討した。多経路プロセスを与える中間多面体種の変化に加えて、逐次的な自己集合の速度論的制御の破れが観察された。この結果により、嵩高さの制御が、5 nm スケールで高い分子複雑性を持つ3次元絡み合い分子材料の構築に有用であることが実証された。

権利情報:

  • In Copyright
    This is the peer reviewed version of the following article: Y. Domoto, R. Nakabayashi, T. Tsurumi, K. Yamamoto, H. Hayashi, Y. Nakamura, M. Fujita, Chem. Asian J. 2025, 20, e202401378, which has been published in final form at https://doi.org/10.1002/asia.202401378. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.

キーワード: Ag cluster, self-assembly, supramolecular chemistry, coordination polyhedra

刊行年月日: 2025-03-17

出版者: Wiley

掲載誌:

  • CHEMISTRY-AN ASIAN JOURNAL (ISSN: 18614728) vol. 20 issue. 6

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5478

公開URL: https://doi.org/10.1002/asia.202401378

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更新時刻: 2025-05-15 14:08:55 +0900

MDRでの公開時刻: 2026-01-02 17:31:01 +0900

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