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Growing energy demand drives the rapid development of clean and reliable energy sources. In the past years, the exploration of novel materials with considerable efficiency and durability has drawn attention in the area of electrochemical energy conversion. Transition metal macrocyclic metallophthalocyanines (MPcs)-based catalysts with a peculiar 2D constitution have emerged with a promising future account of their highly structural tailorability and molecular functionality which greatly extend their functionalities as electrocatalytic materials for energy conversion. This review summarizes the systematic engineering of synthesis of MPcs and their analogs in detail, and mostly pays attention to the frontier research of MPc-based high-performance catalysts toward different electrocatalytic processes concerning hydrogen, oxygen, water, carbon dioxide, and nitrogen, with a particular focus on discussing the interrelationship between the electrocatalytic activity and component/structure, as well as functional applications of MPcs. Finally, we give the gaps that need to be addressed after much thought.

Rights:

• Creative Commons BY Attribution 4.0 International
  

Keyword: Conjugated nanostructure, Electrocatalysis, 2D metallophthalocyanines

Date published: 2024-01-31

Publisher: Wiley

Journal:

• ENERGY & ENVIRONMENTAL MATERIALS (ISSN: 25750356) vol. 7 issue. 4

Funding:

• China Postdoctoral Science Foundation 2020M682352
• National Natural Science Foundation of China 51702291

Manuscript type: Publisher's version (Version of record)

MDR DOI:

First published URL: https://doi.org/10.1002/eem2.12709

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Updated at: 2024-07-16 16:30:26 +0900

Published on MDR: 2024-07-16 16:30:26 +0900