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説明:

Hollow nanostructure materials derived from metal-organic frameworks (MOFs) have many promising applications in electrochemical energy storage and conversion, benefiting from their large specific surface area and void space, accelerating electron and mass transport. Significant efforts have been devoted to designing and fabricating hollow materials with manipulated geometric morphology, optimized electronic structure, and diverse composition. This review summarizes the current research progress of MOF-derived hollow materials for electrocatalysis. Here, we commence with the synthesis strategies for MOF-derived hollow functional materials, providing a comprehensive overview of design approaches for hollow structures. These encompass acid etching, ion exchange, templating methods, and autocatalytic pyrolysis, demonstrating the rich possibilities and advantages in designing and synthesising MOF-derived hollow materials. Subsequently, we focus on representative advances in the application of MOF-derived hollow materials within the field of small-molecule conversion, including hydrogen evolution reactions, oxygen evolution reactions, and oxygen reduction reactions. Finally, synthesis optimization and application prospects of MOF-derived hollow materials are provided.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: metal-organic framework, hollow structure, nanomaterials, controllable synthesis, electrochemical applications

刊行年月日: 2025-12-31

出版者: Tsinghua University Press

掲載誌:

• Nano Research Energy (ISSN: 27910091) vol. 5 issue. 1

研究助成金:

原稿種別: 出版者版 (Version of record)

MDR DOI:

公開URL: https://doi.org/10.26599/nre.2025.9120214

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更新時刻: 2026-03-31 16:07:49 +0900

MDRでの公開時刻: 2026-04-03 08:25:59 +0900