# Fileset

[Ceramics International-V50-43414_Supplement.pdf](https://mdr.nims.go.jp/filesets/cf1847c2-97e5-41df-a3ca-4688bcad6a55/download)

## Creator

[Andreas Dönni](https://orcid.org/0000-0002-7300-9175), Vladimir Y. Pomjakushin, Martin Rotter, [Lei Zhang](https://orcid.org/0000-0003-1173-4328), [Kazunari Yamaura](https://orcid.org/0000-0003-0390-8244), [Alexei A. Belik](https://orcid.org/0000-0001-9031-2355)

## Rights

[In Copyright](http://rightsstatements.org/vocab/InC/1.0/)

## Other metadata

[Ferrimagnetic structures with rare-earth induced spin-reorientation in the Mn self-doped perovskite (Er0.7Mn0.3)MnO3](https://mdr.nims.go.jp/datasets/2a2613da-8d30-4385-8c8a-c71bb26b7695)

## Fulltext

Synthesis and study of vanadates Me3+1 1 Supplementary Tables and Figures  Ferrimagnetic structures with rare-earth induced spin-reorientation in the Mn self-doped perovskite (Er0.7Mn0.3)MnO3 Andreas Dönni, Vladimir Y. Pomjakushin, Martin Rotter, Lei Zhang, Kazunari Yamaura, Alexei A. Belik   Supplementary Table S1. Energy levels of the crystal field (CF) splitting of Er3+ in (Er0.7Mn0.3)MnO3 and (Er0.8Mn0.2)MnO3 based on the point charge model, calculated by McPhase.   Number of  CF level (Er0.7Mn0.3)MnO3 Er3+ energy (meV) (Er0.8Mn0.2)MnO3 Er3+ energy (meV) 16 23.72  36.96(39) 23.25  36.36(39) 15 23.72  36.96(39) 23.25  36.36(39) 14 12.63  25.87(25) 12.36  25.48(23) 13 12.63  25.87(25) 12.36  25.48(23) 12 4.12  17.36(20) 3.63  16.75(16) 11 4.12  17.36(20) 3.63  16.75(16) 10 -0.70  12.54(25) -0.99  12.13(27) 9 -0.70  12.54(25) -0.99  12.13(27) 8 -6.54  6.70(16) -6.13  6.99(17) 7 -6.54  6.70(16) -6.13  6.99(17) 6 -9.69  3.55(25) -8.76  4.36(32) 5 -9.69  3.55(25) -8.76  4.36(32) 4 -10.32  2.92(27) -10.24  2.88(13) 3 -10.32  2.92(27) -10.24  2.88(13) 2 -13.24  0.00(0) -13.12  0.00(0) 1 -13.24  0.00 -13.12  0.00    2 Supplementary Table S2. Induced magnetic Er3+ moments in (Er0.8Mn0.2)MnO3 at T = 1 K in an external magnetic field of H = 10 T applied along the three axes a, b, c calculated by McPhase. Uncertainties due to the experimental errors in the crystal-structural parameters were evaluated using gauss law of error propagation and are shown in parentheses only for Er11 for simplicity.  H || a <Ma> <Mb> <Mc> <M> Er11 3.112(755) 0(0) -1.795(210) 3.592(763) Er12 3.112 0 1.795 3.592 Er13 3.112 0 -1.795 3.592 Er14 3.112 0 1.795 3.592 H || b <Ma> <Mb> <Mc> <M> Er11 0(0) 8.269(33) 0(0) 8.269(33) Er12 0 8.269 0 8.269 Er13 0 8.269 0 8.269 Er14 0 8.269 0 8.269 H || c <Ma> <Mb> <Mc> <M> Er11 -0.838(43) 0(0) 5.765(168) 5.826(172) Er12 0.838 0 5.765 5.826 Er13 -0.838 0 5.765 5.826 Er14 0.838 0 5.765 5.826     3  Supplementary Fig. S1. Experimental (black dots), calculated (red line), and difference (blue line) neutron diffraction pattern of (Er0.7Mn0.3)MnO3 in the paramagnetic state at T = 130 K. No corrections for strain effects were used. The tick marks indicate Bragg peak positions of the crystal structure. Resultant R and χ2 values with and without strain corrections are given.    4   Supplementary Fig. S2. Temperature dependence of specific heat Cp/T of (Er0.7Mn0.3)MnO3 measured on cooling (filled symbols) and heating (empty symbols) at magnetic fields H = 0 Oe and H = 70 kOe. The vertical dashed lines indicate the FiM phase transition at TC = 104 K and the Spin-reorientation temperature at TSR = 11 K at zero field.    5   Supplementary Fig. S3. Temperature dependence of the ordered Mn and Er moments of (Er0.7Mn0.3)MnO3 based on Model #2. The vertical dashed lines indicate the FiM phase transition at TC = 104 K and the Spin-reorientation temperature at TSR = 11 K.    6  Supplementary Fig. S4. Field dependence of the single-ion magnetization in an external magnetic field applied along the a-, b- and c-axes for Er3+ in (Er0.7Mn0.3)MnO3 (a) and (Er0.8Mn0.2)MnO3 (b) at T= 1 K calculated by McPhase.