data_z00151320901_pl_jp_inc_om100_bkg1
_audit_creation_date               2022-07-14
_audit_creation_method
;
Olex2 1.5-ac5-023
(compiled 2022.04.12 svn.rca3783a0 for Rigaku Oxford Diffraction, GUI svn.r6498)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'Ca4 Li2 O13 Si4'
_chemical_formula_sum              'Ca4 Li2 O13 Si4'
_chemical_formula_weight           494.56
_chemical_melting_point            ?
_chemical_oxdiff_formula           'Li2 Ca4 Si4 O13'
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'Ca' 'Ca' 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Li' 'Li' -0.0003 0.0001
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     7.1593(4)
_cell_length_b                     8.2192(4)
_cell_length_c                     10.4182(6)
_cell_angle_alpha                  70.737(5)
_cell_angle_beta                   89.858(4)
_cell_angle_gamma                  77.719(5)
_cell_volume                       563.96(6)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      7346
_cell_measurement_temperature      301.2(8)
_cell_measurement_theta_max        52.1760
_cell_measurement_theta_min        2.6800
_shelx_estimated_absorpt_T_max     0.953
_shelx_estimated_absorpt_T_min     0.909
_exptl_absorpt_coefficient_mu      2.421
_exptl_absorpt_correction_T_max    0.995
_exptl_absorpt_correction_T_min    0.939
_exptl_absorpt_correction_type     gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.53a (Rigaku Oxford Diffraction, 2022)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'light brown'
_exptl_crystal_colour_lustre       ?
_exptl_crystal_colour_modifier     light
_exptl_crystal_colour_primary      brown
_exptl_crystal_density_diffrn      2.912
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         irregular
_exptl_crystal_F_000               492
loop_
  _exptl_crystal_face_index_h
  _exptl_crystal_face_index_k
  _exptl_crystal_face_index_l
  _exptl_crystal_face_perp_dist
 4 4 13 0.0132
 -10 -4 -3 0.0132
 1 -3 -15 0.0119
 -2 10 2 0.0150
 7 -7 -6 0.0158
 -5 -9 4 0.0145
 2 -10 -2 0.0113
 -8 4 7 0.0150
 7 7 -6 0.0217
 4 -4 9 0.0074
 -4 4 -9 0.0112
 10 -1 -2 0.0191
 -4 -3 11 0.0160
 1 10 11 0.0153
 -3 -11 -9 0.0149

_exptl_crystal_size_max            0.04
_exptl_crystal_size_mid            0.03
_exptl_crystal_size_min            0.02
loop_
  _exptl_oxdiff_crystal_face_indexfrac_h
  _exptl_oxdiff_crystal_face_indexfrac_k
  _exptl_oxdiff_crystal_face_indexfrac_l
  _exptl_oxdiff_crystal_face_x
  _exptl_oxdiff_crystal_face_y
  _exptl_oxdiff_crystal_face_z
 4.0143 4.0532 13.4781 0.2298 0.9642 0.1324
 -9.7995 -3.7735 -3.4913 -0.1649 -0.6809 0.7135
 1.2353 -2.6395 -14.5277 -0.1808 -0.7655 -0.6175
 -1.8086 10.4740 2.0541 -0.9639 0.2306 0.1331
 6.6103 -6.6943 -6.1071 0.6810 -0.1649 -0.7135
 -4.9318 -9.0246 3.9348 0.7533 -0.1778 0.6332
 2.1514 -10.3607 -2.3503 0.9578 -0.2293 -0.1734
 -7.8385 4.2342 7.0776 -0.4742 0.1161 0.8727
 6.9905 6.5772 -5.8529 -0.5086 0.1187 -0.8528
 4.3920 -4.0133 8.5824 0.8234 0.5674 -0.0091
 -4.3920 4.0133 -8.5824 -0.8234 -0.5674 0.0091
 9.6285 -0.9333 -2.4604 0.3949 0.2687 -0.8785
 -4.4247 -3.2782 11.1587 0.4832 0.3361 0.8084
 0.8826 10.2376 10.7057 -0.5523 0.8002 0.2337
 -3.0622 -10.8147 -9.1524 0.5674 -0.8234 0.0091

_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0519
_diffrn_reflns_av_unetI/netI       0.0303
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.992
_diffrn_reflns_limit_h_max         10
_diffrn_reflns_limit_h_min         -10
_diffrn_reflns_limit_k_max         11
_diffrn_reflns_limit_k_min         -11
_diffrn_reflns_limit_l_max         14
_diffrn_reflns_limit_l_min         -14
_diffrn_reflns_number              18107
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.992
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           30.507
_diffrn_reflns_theta_min           2.694
_diffrn_ambient_environment        air
_diffrn_ambient_temperature        301.2(8)
_diffrn_detector                   'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean   10.0000
_diffrn_detector_type              'HyPix-Arc 150'
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.992
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω      2.00  31.00   0.10   18.05    --    0.09  21.00-127.97  290
  2  ω      2.00  35.00   0.10   18.05    --    0.09  21.00  94.63  330
  3  ω      2.00  32.00   0.10   18.05    --    0.09  20.00 161.64  300
  4  ω    -35.00  -8.00   0.10   18.05    --    0.09 -21.00-156.25  270
  5  ω    -34.00  -6.00   0.10   18.05    --    0.09 -21.00  12.06  280
  6  ω     10.00  36.00   0.10   18.05    --    0.09  23.00  19.80  260
  7  ω     -2.00  37.00   0.10   18.05    --    2.00  19.00 -16.00  390
  8  ω    -23.00   6.00   0.10   18.05    --   10.00 -19.00 -45.68  290
  9  ω     19.00  50.00   0.10   18.05    --   14.00  22.00 -94.31  310
 10  ω     -9.00  17.00   0.10   18.05    --   18.00 -99.00 108.64  260
 11  ω     -8.00  17.00   0.10   18.05    --   18.00-101.00 -15.35  250
 12  ω     -9.00  17.00   0.10   18.05    --   18.00-100.00  38.30  260
 13  ω     -8.00  19.00   0.10   18.05    --   18.00-101.00 -80.50  270
 14  ω     -9.00  17.00   0.10   18.05    --   18.00 -99.00 164.21  260
 15  ω     -8.00  17.00   0.10   18.05    --   18.00-101.00-144.45  250
 16  ω    -24.00   2.00   0.10   18.05    --  -30.00  22.00 -82.11  260
 17  ω    -28.00  -2.00   0.10   18.05    --  -30.00  21.00 103.57  260
 18  ω    -28.00   1.00   0.10   18.05    --  -30.00  21.00  47.24  290
 19  ω    -20.00   5.00   0.10   18.05    --  -30.00  23.00  69.62  250
 20  ω    -25.00   3.00   0.10   18.05    --  -30.00  17.00  24.31  280
 21  ω    -28.00   3.00   0.10   18.05    --  -30.00  21.00-140.83  310
 22  ω    -20.00   6.00   0.10   18.05    --  -30.00  23.00-167.29  260
 23  ω    -20.00   6.00   0.10   18.05    --  -30.00  23.00-127.36  260
 24  ω    -25.00   0.00   0.10   18.05    --  -30.00  22.00 125.80  250
 25  ω    -28.00   5.00   0.10   18.05    --  -30.00  21.00 -14.98  330
 26  ω    -24.00   5.00   0.10   18.05    --  -30.00  22.00 -53.99  290
 27  ω    -28.00   5.00   0.10   18.05    --  -30.00  21.00 160.68  330
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'ROD, Synergy Custom system, HyPix-Arc 150'
_diffrn_measurement_method         'ω scans'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        0.0404547000
_diffrn_orient_matrix_UB_12        -0.0914153000
_diffrn_orient_matrix_UB_13        0.0324918000
_diffrn_orient_matrix_UB_21        0.0432813000
_diffrn_orient_matrix_UB_22        0.0191156000
_diffrn_orient_matrix_UB_23        0.0528982000
_diffrn_orient_matrix_UB_31        -0.0826226000
_diffrn_orient_matrix_UB_32        -0.0088358000
_diffrn_orient_matrix_UB_33        0.0370884000
_diffrn_radiation_monochromator    mirror
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             'Mo K\a'
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'Rotating-anode X-ray tube'
_diffrn_source_type                'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  3039
_reflns_number_total               3412
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.42.53a (Rigaku OD, 2022)'
_computing_data_collection         'CrysAlisPro 1.171.42.53a (Rigaku OD, 2022)'
_computing_data_reduction          'CrysAlisPro 1.171.42.53a (Rigaku OD, 2022)'
_computing_molecular_graphics      'Olex2 1.5-ac5-023 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5-ac5-023 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max           1.069
_refine_diff_density_min           -0.673
_refine_diff_density_rms           0.158
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.202
_refine_ls_hydrogen_treatment      undef
_refine_ls_matrix_type             full
_refine_ls_number_parameters       208
_refine_ls_number_reflns           3412
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0533
_refine_ls_R_factor_gt             0.0450
_refine_ls_restrained_S_all        1.202
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0476P)²+1.1556P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1047
_refine_ls_wR_factor_ref           0.1085
_refine_special_details            ?
_olex2_refinement_description
;
;
_atom_sites_solution_hydrogens     .
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Ca01 Ca 0.92881(8) 0.29223(8) 0.10560(6) 0.01033(13) Uani 1 1 d . . . . .
 Ca02 Ca 0.07009(8) 0.69707(8) 0.50534(6) 0.01015(13) Uani 1 1 d . . . . .
 Ca03 Ca 0.41678(8) 0.30573(8) 0.49700(6) 0.01070(13) Uani 1 1 d . . . . .
 Ca04 Ca 0.42446(8) 0.28960(8) 0.09733(6) 0.01048(13) Uani 1 1 d . . . . .
 Si01 Si 0.57438(12) 0.58482(11) 0.22141(8) 0.00860(16) Uani 1 1 d . . . . .
 Si02 Si 0.13667(12) 0.59303(11) 0.21937(8) 0.00882(16) Uani 1 1 d . . . . .
 Si03 Si 0.21748(12) 0.11724(11) 0.80437(8) 0.00912(16) Uani 1 1 d . . . . .
 Si04 Si 0.23332(12) 0.07255(11) 0.32133(8) 0.00987(17) Uani 1 1 d . . . . .
 Li01 Li 0.2535(13) 0.9079(9) 0.0922(7) 0.0318(16) Uani 1 1 d . . . . .
 Li02 Li 0.7275(17) 0.0749(10) 0.3856(9) 0.050(3) Uani 1 1 d . . . . .
 O01 O 0.0141(3) 0.1653(3) 0.3412(2) 0.0147(4) Uani 1 1 d . . . . .
 O02 O 0.7133(3) 0.1246(3) 0.5676(2) 0.0131(4) Uani 1 1 d . . . . .
 O03 O 0.4002(3) 0.1765(3) 0.3363(2) 0.0143(4) Uani 1 1 d . . . . .
 O04 O 0.3660(3) 0.5077(3) 0.6200(2) 0.0111(4) Uani 1 1 d . . . . .
 O05 O 0.1179(3) 0.5030(3) 0.3777(2) 0.0108(4) Uani 1 1 d . . . . .
 O06 O 0.1206(3) 0.4900(3) 0.1162(2) 0.0115(4) Uani 1 1 d . . . . .
 O07 O 0.6354(3) 0.4676(3) 0.1259(2) 0.0128(4) Uani 1 1 d . . . . .
 O08 O 0.2286(3) 0.0885(3) 0.1600(2) 0.0114(4) Uani 1 1 d . . . . .
 O09 O 0.0058(3) 0.2080(3) 0.8434(2) 0.0149(4) Uani 1 1 d . . . . .
 O10 O 0.3628(3) 0.2258(3) 0.8470(2) 0.0159(5) Uani 1 1 d . . . . .
 O11 O 0.7269(3) 0.0874(3) 0.1011(2) 0.0120(4) Uani 1 1 d . . . . .
 O12 O 0.2150(3) 0.1490(3) 0.6435(2) 0.0127(4) Uani 1 1 d . . . . .
 O13 O 0.3410(3) 0.6558(3) 0.1981(2) 0.0131(4) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Ca01 Ca04 3.5450(8) 1_655 ?
 Ca01 Si02 3.2069(10) 2_665 ?
 Ca01 Si04 2.9558(10) 1_655 ?
 Ca01 Li01 3.438(7) 2_665 ?
 Ca01 Li02 3.379(10) . ?
 Ca01 O01 2.352(2) 1_655 ?
 Ca01 O06 2.369(2) 1_655 ?
 Ca01 O06 2.382(2) 2_665 ?
 Ca01 O07 2.334(2) . ?
 Ca01 O08 2.363(2) 1_655 ?
 Ca01 O09 3.053(2) 1_654 ?
 Ca01 O11 2.452(2) . ?
 Ca02 Ca03 3.4908(8) 2_566 ?
 Ca02 Si02 3.3668(10) . ?
 Ca02 Si04 3.4906(10) 1_565 ?
 Ca02 Si04 3.4716(10) 2_566 ?
 Ca02 Li02 3.078(10) 2_666 ?
 Ca02 Li02 3.382(9) 1_465 ?
 Ca02 O01 2.258(2) 2_566 ?
 Ca02 O02 2.315(2) 2_666 ?
 Ca02 O04 2.392(2) . ?
 Ca02 O05 2.369(2) 2_566 ?
 Ca02 O05 2.365(2) . ?
 Ca02 O12 2.407(2) 2_566 ?
 Ca03 Si01 3.3939(10) . ?
 Ca03 Si01 3.3445(10) 2_666 ?
 Ca03 Si02 3.3869(10) . ?
 Ca03 Si04 3.4850(10) . ?
 Ca03 Li02 3.089(10) . ?
 Ca03 Li02 3.346(9) 2_656 ?
 Ca03 O02 2.281(2) . ?
 Ca03 O03 2.274(2) . ?
 Ca03 O04 2.382(2) . ?
 Ca03 O04 2.455(2) 2_666 ?
 Ca03 O05 2.441(2) . ?
 Ca03 O12 2.358(2) . ?
 Ca04 Si01 3.4489(10) . ?
 Ca04 Si01 3.1360(10) 2_665 ?
 Ca04 Si02 3.4604(10) . ?
 Ca04 Si04 2.9626(10) . ?
 Ca04 Li02 3.427(10) . ?
 Ca04 O03 2.373(2) . ?
 Ca04 O06 2.484(2) . ?
 Ca04 O07 2.481(2) 2_665 ?
 Ca04 O07 2.396(2) . ?
 Ca04 O08 2.322(2) . ?
 Ca04 O10 2.877(2) 1_554 ?
 Ca04 O11 2.425(2) . ?
 Si01 Li01 3.034(8) . ?
 Si01 O04 1.589(2) 2_666 ?
 Si01 O07 1.600(2) . ?
 Si01 O10 1.642(2) 2_666 ?
 Si01 O13 1.639(2) . ?
 Si02 Li01 2.794(7) . ?
 Si02 O05 1.588(2) . ?
 Si02 O06 1.590(2) . ?
 Si02 O09 1.653(2) 2_566 ?
 Si02 O13 1.643(2) . ?
 Si03 Li01 2.903(7) 1_546 ?
 Si03 Li02 2.891(8) 2_656 ?
 Si03 O09 1.654(2) . ?
 Si03 O10 1.654(2) . ?
 Si03 O11 1.607(2) 2_656 ?
 Si03 O12 1.608(2) . ?
 Si04 Li01 3.098(7) 1_545 ?
 Si04 Li02 2.879(9) 2_656 ?
 Si04 O01 1.637(2) . ?
 Si04 O02 1.616(2) 2_656 ?
 Si04 O03 1.645(2) . ?
 Si04 O08 1.642(2) . ?
 Li01 O08 1.820(7) 1_565 ?
 Li01 O09 2.264(9) 2_566 ?
 Li01 O11 2.006(7) 2_665 ?
 Li01 O13 1.961(7) . ?
 Li02 O01 2.322(12) 1_655 ?
 Li02 O02 2.066(9) . ?
 Li02 O03 2.311(12) . ?
 Li02 O12 1.922(8) 2_656 ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Si02 Ca01 Ca04 93.58(2) 2_665 1_655 ?
 Si02 Ca01 Li01 49.58(12) 2_665 2_665 ?
 Si02 Ca01 Li02 138.26(18) 2_665 . ?
 Si04 Ca01 Ca04 53.29(2) 1_655 1_655 ?
 Si04 Ca01 Si02 137.80(3) 1_655 2_665 ?
 Si04 Ca01 Li01 118.05(13) 1_655 2_665 ?
 Si04 Ca01 Li02 70.64(19) 1_655 . ?
 Si04 Ca01 O09 110.21(5) 1_655 1_654 ?
 Li01 Ca01 Ca04 117.41(14) 2_665 1_655 ?
 Li02 Ca01 Ca04 123.52(19) . 1_655 ?
 Li02 Ca01 Li01 92.8(2) . 2_665 ?
 O01 Ca01 Ca04 81.58(6) 1_655 1_655 ?
 O01 Ca01 Si02 170.17(6) 1_655 2_665 ?
 O01 Ca01 Si04 33.55(6) 1_655 1_655 ?
 O01 Ca01 Li01 125.49(13) 1_655 2_665 ?
 O01 Ca01 Li02 43.4(2) 1_655 . ?
 O01 Ca01 O06 158.30(8) 1_655 2_665 ?
 O01 Ca01 O06 83.75(8) 1_655 1_655 ?
 O01 Ca01 O08 66.48(8) 1_655 1_655 ?
 O01 Ca01 O09 139.71(7) 1_655 1_654 ?
 O01 Ca01 O11 94.92(8) 1_655 . ?
 O06 Ca01 Ca04 88.62(6) 2_665 1_655 ?
 O06 Ca01 Ca04 44.37(6) 1_655 1_655 ?
 O06 Ca01 Si02 28.46(5) 2_665 2_665 ?
 O06 Ca01 Si02 98.83(6) 1_655 2_665 ?
 O06 Ca01 Si04 141.91(6) 2_665 1_655 ?
 O06 Ca01 Si04 76.10(6) 1_655 1_655 ?
 O06 Ca01 Li01 76.20(13) 2_665 2_665 ?
 O06 Ca01 Li01 146.62(13) 1_655 2_665 ?
 O06 Ca01 Li02 120.58(17) 1_655 . ?
 O06 Ca01 Li02 147.0(2) 2_665 . ?
 O06 Ca01 O06 75.78(8) 1_655 2_665 ?
 O06 Ca01 O09 107.57(7) 1_655 1_654 ?
 O06 Ca01 O09 56.12(7) 2_665 1_654 ?
 O06 Ca01 O11 178.33(8) 1_655 . ?
 O06 Ca01 O11 105.41(8) 2_665 . ?
 O07 Ca01 Ca04 141.18(6) . 1_655 ?
 O07 Ca01 Si02 93.56(6) . 2_665 ?
 O07 Ca01 Si04 128.55(6) . 1_655 ?
 O07 Ca01 Li01 95.84(15) . 2_665 ?
 O07 Ca01 Li02 70.18(18) . . ?
 O07 Ca01 O01 95.55(8) . 1_655 ?
 O07 Ca01 O06 80.03(8) . 2_665 ?
 O07 Ca01 O06 96.82(8) . 1_655 ?
 O07 Ca01 O08 162.04(8) . 1_655 ?
 O07 Ca01 O09 120.25(7) . 1_654 ?
 O07 Ca01 O11 82.29(8) . . ?
 O08 Ca01 Ca04 40.40(5) 1_655 1_655 ?
 O08 Ca01 Si02 104.35(6) 1_655 2_665 ?
 O08 Ca01 Si04 33.68(5) 1_655 1_655 ?
 O08 Ca01 Li01 94.82(15) 1_655 2_665 ?
 O08 Ca01 Li02 94.92(18) 1_655 . ?
 O08 Ca01 O06 116.64(8) 1_655 2_665 ?
 O08 Ca01 O06 81.92(8) 1_655 1_655 ?
 O08 Ca01 O09 76.80(7) 1_655 1_654 ?
 O08 Ca01 O11 98.49(8) 1_655 . ?
 O09 Ca01 Ca04 80.99(5) 1_654 1_655 ?
 O09 Ca01 Si02 30.49(5) 1_654 2_665 ?
 O09 Ca01 Li01 40.29(14) 1_654 2_665 ?
 O09 Ca01 Li02 129.52(15) 1_654 . ?
 O11 Ca01 Ca04 136.49(6) . 1_655 ?
 O11 Ca01 Si02 82.66(6) . 2_665 ?
 O11 Ca01 Si04 103.33(6) . 1_655 ?
 O11 Ca01 Li01 35.02(13) . 2_665 ?
 O11 Ca01 Li02 57.79(17) . . ?
 O11 Ca01 O09 74.10(7) . 1_654 ?
 Si02 Ca02 Ca03 94.30(2) . 2_566 ?
 Si02 Ca02 Si04 146.98(3) . 2_566 ?
 Si02 Ca02 Si04 84.01(2) . 1_565 ?
 Si02 Ca02 Li02 100.28(15) . 1_465 ?
 Si04 Ca02 Ca03 121.60(2) 1_565 2_566 ?
 Si04 Ca02 Ca03 60.07(2) 2_566 2_566 ?
 Si04 Ca02 Si04 92.15(2) 2_566 1_565 ?
 Li02 Ca02 Ca03 58.23(19) 1_465 2_566 ?
 Li02 Ca02 Ca03 127.6(2) 2_666 2_566 ?
 Li02 Ca02 Si02 129.15(19) 2_666 . ?
 Li02 Ca02 Si04 68.0(2) 2_666 2_566 ?
 Li02 Ca02 Si04 64.70(18) 1_465 1_565 ?
 Li02 Ca02 Si04 51.52(17) 2_666 1_565 ?
 Li02 Ca02 Si04 49.66(15) 1_465 2_566 ?
 Li02 Ca02 Li02 83.3(3) 2_666 1_465 ?
 O01 Ca02 Ca03 81.51(6) 2_566 2_566 ?
 O01 Ca02 Si02 165.23(7) 2_566 . ?
 O01 Ca02 Si04 86.16(6) 2_566 1_565 ?
 O01 Ca02 Si04 22.64(6) 2_566 2_566 ?
 O01 Ca02 Li02 48.7(2) 2_566 2_666 ?
 O01 Ca02 Li02 65.45(16) 2_566 1_465 ?
 O01 Ca02 O02 87.92(9) 2_566 2_666 ?
 O01 Ca02 O04 98.37(8) 2_566 . ?
 O01 Ca02 O05 166.10(9) 2_566 . ?
 O01 Ca02 O05 86.08(8) 2_566 2_566 ?
 O01 Ca02 O12 94.11(8) 2_566 2_566 ?
 O02 Ca02 Ca03 143.74(6) 2_666 2_566 ?
 O02 Ca02 Si02 87.21(6) 2_666 . ?
 O02 Ca02 Si04 101.56(6) 2_666 2_566 ?
 O02 Ca02 Si04 22.49(6) 2_666 1_565 ?
 O02 Ca02 Li02 42.15(19) 2_666 2_666 ?
 O02 Ca02 Li02 85.80(19) 2_666 1_465 ?
 O02 Ca02 O04 77.35(8) 2_666 . ?
 O02 Ca02 O05 168.72(8) 2_666 2_566 ?
 O02 Ca02 O05 105.52(8) 2_666 . ?
 O02 Ca02 O12 104.77(8) 2_666 2_566 ?
 O04 Ca02 Ca03 138.38(6) . 2_566 ?
 O04 Ca02 Si02 94.16(6) . . ?
 O04 Ca02 Si04 118.77(6) . 2_566 ?
 O04 Ca02 Si04 99.79(6) . 1_565 ?
 O04 Ca02 Li02 157.23(18) . 1_465 ?
 O04 Ca02 Li02 73.90(19) . 2_666 ?
 O04 Ca02 O12 167.43(8) . 2_566 ?
 O05 Ca02 Ca03 44.29(5) 2_566 2_566 ?
 O05 Ca02 Ca03 89.36(6) . 2_566 ?
 O05 Ca02 Si02 25.24(5) . . ?
 O05 Ca02 Si02 100.87(6) 2_566 . ?
 O05 Ca02 Si04 75.95(6) 2_566 2_566 ?
 O05 Ca02 Si04 164.95(6) 2_566 1_565 ?
 O05 Ca02 Si04 107.60(6) . 1_565 ?
 O05 Ca02 Si04 149.32(6) . 2_566 ?
 O05 Ca02 Li02 142.6(2) . 2_666 ?
 O05 Ca02 Li02 118.16(16) . 1_465 ?
 O05 Ca02 Li02 128.65(19) 2_566 2_666 ?
 O05 Ca02 Li02 100.31(19) 2_566 1_465 ?
 O05 Ca02 O04 81.51(8) . . ?
 O05 Ca02 O04 94.08(8) 2_566 . ?
 O05 Ca02 O05 80.08(8) . 2_566 ?
 O05 Ca02 O12 86.00(8) . 2_566 ?
 O05 Ca02 O12 85.20(8) 2_566 2_566 ?
 O12 Ca02 Ca03 42.35(5) 2_566 2_566 ?
 O12 Ca02 Si02 73.71(6) 2_566 . ?
 O12 Ca02 Si04 82.53(6) 2_566 1_565 ?
 O12 Ca02 Si04 73.27(6) 2_566 2_566 ?
 O12 Ca02 Li02 116.18(19) 2_566 2_666 ?
 O12 Ca02 Li02 33.75(17) 2_566 1_465 ?
 Si01 Ca03 Si01 114.27(2) 2_666 . ?
 Si01 Ca03 Si02 118.63(3) 2_666 . ?
 Si01 Ca03 Si04 96.26(2) . . ?
 Si01 Ca03 Si04 147.79(3) 2_666 . ?
 Si01 Ca03 Li02 101.36(15) 2_666 2_656 ?
 Si02 Ca03 Si01 54.79(2) . . ?
 Si02 Ca03 Si04 70.29(2) . . ?
 Li02 Ca03 Si01 73.26(16) . . ?
 Li02 Ca03 Si01 144.19(15) 2_656 . ?
 Li02 Ca03 Si01 130.7(2) . 2_666 ?
 Li02 Ca03 Si02 111.21(19) 2_656 . ?
 Li02 Ca03 Si02 105.30(18) . . ?
 Li02 Ca03 Si04 49.80(16) 2_656 . ?
 Li02 Ca03 Si04 66.2(2) . . ?
 Li02 Ca03 Li02 81.1(3) . 2_656 ?
 O02 Ca03 Si01 89.00(6) . 2_666 ?
 O02 Ca03 Si01 93.71(6) . . ?
 O02 Ca03 Si02 143.67(6) . . ?
 O02 Ca03 Si04 99.48(6) . . ?
 O02 Ca03 Li02 83.0(2) . 2_656 ?
 O02 Ca03 Li02 42.0(2) . . ?
 O02 Ca03 O04 107.74(8) . . ?
 O02 Ca03 O04 76.70(8) . 2_666 ?
 O02 Ca03 O05 169.02(8) . . ?
 O02 Ca03 O12 102.96(8) . . ?
 O03 Ca03 Si01 167.89(6) . 2_666 ?
 O03 Ca03 Si01 77.58(6) . . ?
 O03 Ca03 Si02 69.61(6) . . ?
 O03 Ca03 Si04 22.82(6) . . ?
 O03 Ca03 Li02 66.68(16) . 2_656 ?
 O03 Ca03 Li02 48.2(2) . . ?
 O03 Ca03 O02 87.67(9) . . ?
 O03 Ca03 O04 96.03(8) . 2_666 ?
 O03 Ca03 O04 163.32(9) . . ?
 O03 Ca03 O05 83.75(8) . . ?
 O03 Ca03 O12 95.09(8) . . ?
 O04 Ca03 Si01 25.90(5) . 2_666 ?
 O04 Ca03 Si01 25.67(5) 2_666 . ?
 O04 Ca03 Si01 94.52(6) 2_666 2_666 ?
 O04 Ca03 Si01 94.66(6) . . ?
 O04 Ca03 Si02 93.82(6) . . ?
 O04 Ca03 Si02 77.94(5) 2_666 . ?
 O04 Ca03 Si04 117.65(6) 2_666 . ?
 O04 Ca03 Si04 149.87(6) . . ?
 O04 Ca03 Li02 153.97(18) 2_666 2_656 ?
 O04 Ca03 Li02 72.92(18) 2_666 . ?
 O04 Ca03 Li02 120.38(16) . 2_656 ?
 O04 Ca03 Li02 143.9(2) . . ?
 O04 Ca03 O04 81.79(8) . 2_666 ?
 O04 Ca03 O05 80.15(8) . . ?
 O05 Ca03 Si01 100.77(6) . 2_666 ?
 O05 Ca03 Si01 77.78(5) . . ?
 O05 Ca03 Si02 25.64(5) . . ?
 O05 Ca03 Si04 74.89(6) . . ?
 O05 Ca03 Li02 127.65(19) . . ?
 O05 Ca03 Li02 99.7(2) . 2_656 ?
 O05 Ca03 O04 97.36(7) . 2_666 ?
 O12 Ca03 Si01 161.57(6) . . ?
 O12 Ca03 Si01 74.33(6) . 2_666 ?
 O12 Ca03 Si02 106.85(6) . . ?
 O12 Ca03 Si04 73.49(6) . . ?
 O12 Ca03 Li02 114.48(18) . . ?
 O12 Ca03 Li02 34.14(17) . 2_656 ?
 O12 Ca03 O04 168.84(8) . 2_666 ?
 O12 Ca03 O04 87.78(8) . . ?
 O12 Ca03 O05 84.67(8) . . ?
 Si01 Ca04 Si01 110.38(2) 2_665 . ?
 Si01 Ca04 Si02 113.89(3) 2_665 . ?
 Si01 Ca04 Si02 53.69(2) . . ?
 Si01 Ca04 Li02 141.11(18) 2_665 . ?
 Si04 Ca04 Si01 140.27(3) . 2_665 ?
 Si04 Ca04 Si01 105.82(3) . . ?
 Si04 Ca04 Si02 75.60(3) . . ?
 Si04 Ca04 Li02 68.30(18) . . ?
 Li02 Ca04 Si01 68.61(13) . . ?
 Li02 Ca04 Si02 96.81(15) . . ?
 O03 Ca04 Si01 75.29(6) . . ?
 O03 Ca04 Si01 173.92(6) . 2_665 ?
 O03 Ca04 Si02 67.33(6) . . ?
 O03 Ca04 Si04 33.67(6) . . ?
 O03 Ca04 Li02 42.27(19) . . ?
 O03 Ca04 O06 80.38(8) . . ?
 O03 Ca04 O07 152.23(8) . 2_665 ?
 O03 Ca04 O07 91.14(8) . . ?
 O03 Ca04 O10 143.04(7) . 1_554 ?
 O03 Ca04 O11 94.63(8) . . ?
 O06 Ca04 Si01 98.61(5) . 2_665 ?
 O06 Ca04 Si01 76.34(5) . . ?
 O06 Ca04 Si02 24.71(5) . . ?
 O06 Ca04 Si04 74.37(5) . . ?
 O06 Ca04 Li02 117.68(17) . . ?
 O06 Ca04 O10 104.31(7) . 1_554 ?
 O07 Ca04 Si01 94.94(6) . 2_665 ?
 O07 Ca04 Si01 86.04(6) 2_665 . ?
 O07 Ca04 Si01 30.34(5) 2_665 2_665 ?
 O07 Ca04 Si01 24.19(5) . . ?
 O07 Ca04 Si02 76.48(6) . . ?
 O07 Ca04 Si02 85.09(5) 2_665 . ?
 O07 Ca04 Si04 124.51(6) . . ?
 O07 Ca04 Si04 143.51(6) 2_665 . ?
 O07 Ca04 Li02 145.89(18) 2_665 . ?
 O07 Ca04 Li02 68.67(17) . . ?
 O07 Ca04 O06 96.84(8) . . ?
 O07 Ca04 O06 75.28(7) 2_665 . ?
 O07 Ca04 O07 78.84(8) . 2_665 ?
 O07 Ca04 O10 123.82(7) . 1_554 ?
 O07 Ca04 O10 58.21(7) 2_665 1_554 ?
 O07 Ca04 O11 81.60(8) . . ?
 O08 Ca04 Si01 107.18(6) . 2_665 ?
 O08 Ca04 Si01 138.06(6) . . ?
 O08 Ca04 Si02 94.18(6) . . ?
 O08 Ca04 Si04 33.51(5) . . ?
 O08 Ca04 Li02 93.07(18) . . ?
 O08 Ca04 O03 66.75(8) . . ?
 O08 Ca04 O06 80.29(8) . . ?
 O08 Ca04 O07 157.88(8) . . ?
 O08 Ca04 O07 120.84(8) . 2_665 ?
 O08 Ca04 O10 77.80(7) . 1_554 ?
 O08 Ca04 O11 99.26(8) . . ?
 O10 Ca04 Si01 31.32(5) 1_554 2_665 ?
 O10 Ca04 Si01 141.67(5) 1_554 . ?
 O10 Ca04 Si02 127.58(5) 1_554 . ?
 O10 Ca04 Si04 111.25(5) 1_554 . ?
 O10 Ca04 Li02 134.89(15) 1_554 . ?
 O11 Ca04 Si01 86.52(6) . 2_665 ?
 O11 Ca04 Si01 100.96(6) . . ?
 O11 Ca04 Si02 150.99(6) . . ?
 O11 Ca04 Si04 102.35(6) . . ?
 O11 Ca04 Li02 57.09(17) . . ?
 O11 Ca04 O06 174.77(8) . . ?
 O11 Ca04 O07 109.18(8) . 2_665 ?
 O11 Ca04 O10 80.62(7) . 1_554 ?
 Ca01 Si01 Ca02 68.82(2) . 2_666 ?
 Ca03 Si01 Ca01 103.31(3) . . ?
 Ca03 Si01 Ca01 130.07(3) 2_666 . ?
 Ca03 Si01 Ca02 62.98(2) 2_666 2_666 ?
 Ca03 Si01 Ca02 62.95(2) . 2_666 ?
 Ca03 Si01 Ca03 65.73(2) 2_666 . ?
 Ca03 Si01 Ca04 141.45(3) 2_666 . ?
 Ca03 Si01 Ca04 75.92(2) . . ?
 Ca04 Si01 Ca01 61.667(19) . . ?
 Ca04 Si01 Ca01 67.63(2) 2_665 . ?
 Ca04 Si01 Ca02 133.23(3) 2_665 2_666 ?
 Ca04 Si01 Ca02 103.33(3) . 2_666 ?
 Ca04 Si01 Ca03 146.88(3) 2_665 2_666 ?
 Ca04 Si01 Ca03 144.49(3) 2_665 . ?
 Ca04 Si01 Ca04 69.62(2) 2_665 . ?
 Li01 Si01 Ca01 136.84(13) . . ?
 Li01 Si01 Ca02 152.67(13) . 2_666 ?
 Li01 Si01 Ca03 109.05(14) . . ?
 Li01 Si01 Ca03 89.75(13) . 2_666 ?
 Li01 Si01 Ca04 99.36(14) . . ?
 Li01 Si01 Ca04 69.42(13) . 2_665 ?
 O04 Si01 Ca01 97.11(9) 2_666 . ?
 O04 Si01 Ca02 30.42(8) 2_666 2_666 ?
 O04 Si01 Ca03 40.90(8) 2_666 2_666 ?
 O04 Si01 Ca03 42.00(8) 2_666 . ?
 O04 Si01 Ca04 163.65(9) 2_666 2_665 ?
 O04 Si01 Ca04 109.15(9) 2_666 . ?
 O04 Si01 Li01 126.05(15) 2_666 . ?
 O04 Si01 O07 117.06(13) 2_666 . ?
 O04 Si01 O10 114.28(12) 2_666 2_666 ?
 O04 Si01 O13 109.35(12) 2_666 . ?
 O07 Si01 Ca01 28.87(8) . . ?
 O07 Si01 Ca02 93.68(9) . 2_666 ?
 O07 Si01 Ca03 103.58(9) . . ?
 O07 Si01 Ca03 156.61(9) . 2_666 ?
 O07 Si01 Ca04 51.55(9) . 2_665 ?
 O07 Si01 Ca04 37.85(8) . . ?
 O07 Si01 Li01 113.62(16) . . ?
 O07 Si01 O10 108.35(13) . 2_666 ?
 O07 Si01 O13 106.96(12) . . ?
 O10 Si01 Ca01 101.62(9) 2_666 . ?
 O10 Si01 Ca02 108.27(9) 2_666 2_666 ?
 O10 Si01 Ca03 147.46(10) 2_666 . ?
 O10 Si01 Ca03 82.24(9) 2_666 2_666 ?
 O10 Si01 Ca04 65.59(9) 2_666 2_665 ?
 O10 Si01 Ca04 135.18(9) 2_666 . ?
 O10 Si01 Li01 63.27(17) 2_666 . ?
 O13 Si01 Ca01 135.58(9) . . ?
 O13 Si01 Ca02 138.35(9) . 2_666 ?
 O13 Si01 Ca03 91.30(9) . 2_666 ?
 O13 Si01 Ca03 77.01(8) . . ?
 O13 Si01 Ca04 86.42(9) . 2_665 ?
 O13 Si01 Ca04 75.95(9) . . ?
 O13 Si01 Li01 36.01(17) . . ?
 O13 Si01 O10 99.12(12) . 2_666 ?
 Ca01 Si02 Ca01 66.07(2) 2_665 1_455 ?
 Ca01 Si02 Ca02 132.01(3) 2_665 2_566 ?
 Ca01 Si02 Ca02 149.11(3) 2_665 . ?
 Ca01 Si02 Ca03 144.16(3) 2_665 . ?
 Ca01 Si02 Ca04 68.75(2) 2_665 . ?
 Ca02 Si02 Ca01 68.51(2) 2_566 1_455 ?
 Ca02 Si02 Ca01 129.13(3) . 1_455 ?
 Ca02 Si02 Ca02 62.42(2) . 2_566 ?
 Ca02 Si02 Ca03 65.37(2) . . ?
 Ca02 Si02 Ca04 141.11(3) . . ?
 Ca03 Si02 Ca01 100.92(3) . 1_455 ?
 Ca03 Si02 Ca02 59.700(19) . 2_566 ?
 Ca03 Si02 Ca04 75.86(2) . . ?
 Ca04 Si02 Ca01 59.853(19) . 1_455 ?
 Ca04 Si02 Ca02 100.83(2) . 2_566 ?
 Li01 Si02 Ca01 69.51(15) . 2_665 ?
 Li01 Si02 Ca01 135.58(15) . 1_455 ?
 Li01 Si02 Ca02 152.34(14) . 2_566 ?
 Li01 Si02 Ca02 90.40(14) . . ?
 Li01 Si02 Ca03 115.55(17) . . ?
 Li01 Si02 Ca04 104.13(16) . . ?
 O05 Si02 Ca01 96.78(9) . 1_455 ?
 O05 Si02 Ca01 161.63(9) . 2_665 ?
 O05 Si02 Ca02 39.41(8) . . ?
 O05 Si02 Ca02 29.63(8) . 2_566 ?
 O05 Si02 Ca03 41.69(8) . . ?
 O05 Si02 Ca04 109.33(9) . . ?
 O05 Si02 Li01 127.21(16) . . ?
 O05 Si02 O06 120.64(12) . . ?
 O05 Si02 O09 112.22(12) . 2_566 ?
 O05 Si02 O13 108.97(12) . . ?
 O06 Si02 Ca01 28.60(8) . 1_455 ?
 O06 Si02 Ca01 45.58(8) . 2_665 ?
 O06 Si02 Ca02 95.20(8) . 2_566 ?
 O06 Si02 Ca02 157.38(9) . . ?
 O06 Si02 Ca03 107.51(9) . . ?
 O06 Si02 Ca04 40.79(8) . . ?
 O06 Si02 Li01 111.48(16) . . ?
 O06 Si02 O09 108.08(12) . 2_566 ?
 O06 Si02 O13 107.10(12) . . ?
 O09 Si02 Ca01 69.61(9) 2_566 2_665 ?
 O09 Si02 Ca01 107.75(9) 2_566 1_455 ?
 O09 Si02 Ca02 79.63(9) 2_566 . ?
 O09 Si02 Ca02 111.68(9) 2_566 2_566 ?
 O09 Si02 Ca03 144.02(9) 2_566 . ?
 O09 Si02 Ca04 137.84(9) 2_566 . ?
 O09 Si02 Li01 54.13(19) 2_566 . ?
 O13 Si02 Ca01 88.52(9) . 2_665 ?
 O13 Si02 Ca01 133.93(9) . 1_455 ?
 O13 Si02 Ca02 135.85(9) . 2_566 ?
 O13 Si02 Ca02 92.56(9) . . ?
 O13 Si02 Ca03 77.19(8) . . ?
 O13 Si02 Ca04 75.54(9) . . ?
 O13 Si02 Li01 43.5(2) . . ?
 O13 Si02 O09 97.16(12) . 2_566 ?
 Ca01 Si03 Ca04 60.693(19) 2_656 2_656 ?
 Ca02 Si03 Ca01 93.72(2) 2_566 2_656 ?
 Ca02 Si03 Ca04 125.42(3) 2_566 2_656 ?
 Ca03 Si03 Ca01 124.16(3) . 2_656 ?
 Ca03 Si03 Ca02 59.479(19) . 2_566 ?
 Ca03 Si03 Ca04 94.24(2) . 2_656 ?
 Li01 Si03 Ca01 63.23(15) 1_546 2_656 ?
 Li01 Si03 Ca02 147.91(17) 1_546 2_566 ?
 Li01 Si03 Ca03 151.70(18) 1_546 . ?
 Li01 Si03 Ca04 64.48(15) 1_546 2_656 ?
 Li02 Si03 Ca01 62.06(19) 2_656 2_656 ?
 Li02 Si03 Ca02 62.7(2) 2_656 2_566 ?
 Li02 Si03 Ca03 62.10(19) 2_656 . ?
 Li02 Si03 Ca04 62.7(2) 2_656 2_656 ?
 Li02 Si03 Li01 116.8(2) 2_656 1_546 ?
 O09 Si03 Ca01 88.51(9) . 2_656 ?
 O09 Si03 Ca02 74.59(9) . 2_566 ?
 O09 Si03 Ca03 122.84(9) . . ?
 O09 Si03 Ca04 141.90(9) . 2_656 ?
 O09 Si03 Li01 82.38(19) . 1_546 ?
 O09 Si03 Li02 124.4(3) . 2_656 ?
 O09 Si03 O10 103.22(13) . . ?
 O10 Si03 Ca01 145.09(9) . 2_656 ?
 O10 Si03 Ca02 121.01(9) . 2_566 ?
 O10 Si03 Ca03 76.70(9) . . ?
 O10 Si03 Ca04 92.88(9) . 2_656 ?
 O10 Si03 Li01 85.56(18) . 1_546 ?
 O10 Si03 Li02 128.4(3) . 2_656 ?
 O11 Si03 Ca01 35.88(8) 2_656 2_656 ?
 O11 Si03 Ca02 127.15(9) 2_656 2_566 ?
 O11 Si03 Ca03 125.67(9) 2_656 . ?
 O11 Si03 Ca04 33.65(8) 2_656 2_656 ?
 O11 Si03 Li01 41.52(16) 2_656 1_546 ?
 O11 Si03 Li02 75.37(19) 2_656 2_656 ?
 O11 Si03 O09 108.38(12) 2_656 . ?
 O11 Si03 O10 109.79(12) 2_656 . ?
 O11 Si03 O12 114.10(12) 2_656 . ?
 O12 Si03 Ca01 95.32(9) . 2_656 ?
 O12 Si03 Ca02 35.61(8) . 2_566 ?
 O12 Si03 Ca03 34.03(8) . . ?
 O12 Si03 Ca04 95.50(9) . 2_656 ?
 O12 Si03 Li01 155.53(16) . 1_546 ?
 O12 Si03 Li02 38.75(19) . 2_656 ?
 O12 Si03 O09 110.19(12) . . ?
 O12 Si03 O10 110.58(12) . . ?
 Ca01 Si04 Ca02 106.47(3) 1_455 1_545 ?
 Ca01 Si04 Ca02 78.43(3) 1_455 2_566 ?
 Ca01 Si04 Ca03 156.36(3) 1_455 2_656 ?
 Ca01 Si04 Ca03 114.36(3) 1_455 . ?
 Ca01 Si04 Ca04 73.59(3) 1_455 . ?
 Ca01 Si04 Li01 71.65(15) 1_455 1_545 ?
 Ca02 Si04 Ca02 87.85(2) 2_566 1_545 ?
 Ca02 Si04 Ca03 60.24(2) 2_566 . ?
 Ca02 Si04 Ca03 120.19(3) 2_566 2_656 ?
 Ca02 Si04 Ca03 63.17(2) 1_545 2_656 ?
 Ca03 Si04 Ca02 119.17(3) . 1_545 ?
 Ca03 Si04 Ca03 88.67(2) . 2_656 ?
 Ca04 Si04 Ca02 115.69(3) . 2_566 ?
 Ca04 Si04 Ca02 155.40(3) . 1_545 ?
 Ca04 Si04 Ca03 106.69(3) . 2_656 ?
 Ca04 Si04 Ca03 81.07(3) . . ?
 Ca04 Si04 Li01 73.26(14) . 1_545 ?
 Li01 Si04 Ca02 144.79(17) 1_545 2_566 ?
 Li01 Si04 Ca02 83.34(13) 1_545 1_545 ?
 Li01 Si04 Ca03 150.81(16) 1_545 . ?
 Li01 Si04 Ca03 85.66(15) 1_545 2_656 ?
 Li02 Si04 Ca01 137.7(2) 2_656 1_455 ?
 Li02 Si04 Ca02 63.55(19) 2_656 2_566 ?
 Li02 Si04 Ca02 56.82(19) 2_656 1_545 ?
 Li02 Si04 Ca03 56.73(19) 2_656 2_656 ?
 Li02 Si04 Ca03 62.58(18) 2_656 . ?
 Li02 Si04 Ca04 138.7(2) 2_656 . ?
 Li02 Si04 Li01 133.5(2) 2_656 1_545 ?
 O01 Si04 Ca01 52.54(8) . 1_455 ?
 O01 Si04 Ca02 80.10(9) . 1_545 ?
 O01 Si04 Ca02 32.07(8) . 2_566 ?
 O01 Si04 Ca03 90.66(9) . . ?
 O01 Si04 Ca03 137.00(9) . 2_656 ?
 O01 Si04 Ca04 115.65(9) . . ?
 O01 Si04 Li01 112.72(19) . 1_545 ?
 O01 Si04 Li02 85.3(2) . 2_656 ?
 O01 Si04 O03 116.13(13) . . ?
 O01 Si04 O08 104.00(12) . . ?
 O02 Si04 Ca01 138.52(9) 2_656 1_455 ?
 O02 Si04 Ca02 33.22(8) 2_656 1_545 ?
 O02 Si04 Ca02 101.88(9) 2_656 2_566 ?
 O02 Si04 Ca03 100.48(9) 2_656 . ?
 O02 Si04 Ca03 30.78(8) 2_656 2_656 ?
 O02 Si04 Ca04 136.33(9) 2_656 . ?
 O02 Si04 Li01 89.03(15) 2_656 1_545 ?
 O02 Si04 Li02 44.53(17) 2_656 2_656 ?
 O02 Si04 O01 107.99(12) 2_656 . ?
 O02 Si04 O03 108.50(12) 2_656 . ?
 O02 Si04 O08 116.90(12) 2_656 . ?
 O03 Si04 Ca01 112.98(9) . 1_455 ?
 O03 Si04 Ca02 89.98(9) . 2_566 ?
 O03 Si04 Ca02 139.17(9) . 1_545 ?
 O03 Si04 Ca03 32.42(8) . . ?
 O03 Si04 Ca03 83.28(9) . 2_656 ?
 O03 Si04 Ca04 53.11(8) . . ?
 O03 Si04 Li01 118.40(18) . 1_545 ?
 O03 Si04 Li02 86.0(2) . 2_656 ?
 O08 Si04 Ca01 52.93(8) . 1_455 ?
 O08 Si04 Ca02 131.14(9) . 2_566 ?
 O08 Si04 Ca02 108.30(8) . 1_545 ?
 O08 Si04 Ca03 132.08(9) . . ?
 O08 Si04 Ca03 108.03(9) . 2_656 ?
 O08 Si04 Ca04 51.32(8) . . ?
 O08 Si04 Li01 28.03(15) . 1_545 ?
 O08 Si04 Li02 161.43(18) . 2_656 ?
 O08 Si04 O03 103.60(12) . . ?
 Ca01 Li01 Ca01 112.8(2) 2_665 1_465 ?
 Ca01 Li01 Ca04 59.32(11) 1_465 1_565 ?
 Ca01 Li01 Ca04 146.2(2) 2_665 1_565 ?
 Ca01 Li01 Ca04 62.69(12) 2_665 2_665 ?
 Ca04 Li01 Ca01 147.7(2) 2_665 1_465 ?
 Ca04 Li01 Ca04 105.2(2) 2_665 1_565 ?
 Si01 Li01 Ca01 151.0(2) . 1_465 ?
 Si01 Li01 Ca01 92.27(18) . 2_665 ?
 Si01 Li01 Ca04 107.2(2) . 1_565 ?
 Si01 Li01 Ca04 56.66(13) . 2_665 ?
 Si01 Li01 Si04 98.8(2) . 1_565 ?
 Si02 Li01 Ca01 114.3(3) . 1_465 ?
 Si02 Li01 Ca01 60.91(14) . 2_665 ?
 Si02 Li01 Ca04 152.6(2) . 1_565 ?
 Si02 Li01 Ca04 91.96(18) . 2_665 ?
 Si02 Li01 Si01 64.59(15) . . ?
 Si02 Li01 Si03 128.6(3) . 1_564 ?
 Si02 Li01 Si04 102.2(2) . 1_565 ?
 Si03 Li01 Ca01 81.26(17) 1_564 1_465 ?
 Si03 Li01 Ca01 67.83(15) 1_564 2_665 ?
 Si03 Li01 Ca04 78.38(16) 1_564 1_565 ?
 Si03 Li01 Ca04 67.32(14) 1_564 2_665 ?
 Si03 Li01 Si01 123.3(3) 1_564 . ?
 Si03 Li01 Si04 123.0(2) 1_564 1_565 ?
 Si04 Li01 Ca01 153.2(3) 1_565 2_665 ?
 Si04 Li01 Ca01 52.31(11) 1_565 1_465 ?
 Si04 Li01 Ca04 51.65(11) 1_565 1_565 ?
 Si04 Li01 Ca04 142.8(3) 1_565 2_665 ?
 O08 Li01 Ca01 37.06(19) 1_565 1_465 ?
 O08 Li01 Ca01 149.8(4) 1_565 2_665 ?
 O08 Li01 Ca04 138.2(4) 1_565 2_665 ?
 O08 Li01 Ca04 33.30(17) 1_565 1_565 ?
 O08 Li01 Si01 117.3(4) 1_565 . ?
 O08 Li01 Si02 124.5(3) 1_565 . ?
 O08 Li01 Si03 97.9(3) 1_565 1_564 ?
 O08 Li01 Si04 25.09(13) 1_565 1_565 ?
 O08 Li01 O09 104.8(4) 1_565 2_566 ?
 O08 Li01 O11 129.5(4) 1_565 2_665 ?
 O08 Li01 O13 125.5(4) 1_565 . ?
 O09 Li01 Ca01 60.69(18) 2_566 2_665 ?
 O09 Li01 Ca01 80.9(2) 2_566 1_465 ?
 O09 Li01 Ca04 137.4(3) 2_566 1_565 ?
 O09 Li01 Ca04 117.0(3) 2_566 2_665 ?
 O09 Li01 Si01 100.6(2) 2_566 . ?
 O09 Li01 Si02 36.27(12) 2_566 . ?
 O09 Li01 Si03 112.0(3) 2_566 1_564 ?
 O09 Li01 Si04 93.1(2) 2_566 1_565 ?
 O11 Li01 Ca01 44.54(17) 2_665 2_665 ?
 O11 Li01 Ca01 110.5(3) 2_665 1_465 ?
 O11 Li01 Ca04 41.90(17) 2_665 2_665 ?
 O11 Li01 Ca04 104.4(3) 2_665 1_565 ?
 O11 Li01 Si01 97.4(3) 2_665 . ?
 O11 Li01 Si02 102.7(3) 2_665 . ?
 O11 Li01 Si03 32.07(12) 2_665 1_564 ?
 O11 Li01 Si04 154.3(3) 2_665 1_565 ?
 O11 Li01 O09 103.2(3) 2_665 2_566 ?
 O13 Li01 Ca01 77.4(2) . 2_665 ?
 O13 Li01 Ca01 140.4(3) . 1_465 ?
 O13 Li01 Ca04 131.3(3) . 1_565 ?
 O13 Li01 Ca04 71.8(2) . 2_665 ?
 O13 Li01 Si01 29.42(15) . . ?
 O13 Li01 Si02 35.22(14) . . ?
 O13 Li01 Si03 134.9(3) . 1_564 ?
 O13 Li01 Si04 100.9(3) . 1_565 ?
 O13 Li01 O09 71.2(2) . 2_566 ?
 O13 Li01 O11 103.0(3) . 2_665 ?
 Ca01 Li02 Ca02 99.9(3) . 1_645 ?
 Ca01 Li02 Ca04 64.20(16) . . ?
 Ca02 Li02 Ca01 78.3(2) 2_666 . ?
 Ca02 Li02 Ca02 96.7(3) 2_666 1_645 ?
 Ca02 Li02 Ca03 138.9(3) 2_666 2_656 ?
 Ca02 Li02 Ca03 73.02(17) 2_666 . ?
 Ca02 Li02 Ca04 117.0(2) 2_666 . ?
 Ca02 Li02 Ca04 136.6(3) 1_645 . ?
 Ca03 Li02 Ca01 136.9(3) 2_656 . ?
 Ca03 Li02 Ca01 116.1(2) . . ?
 Ca03 Li02 Ca02 62.52(14) 2_656 1_645 ?
 Ca03 Li02 Ca02 138.7(3) . 1_645 ?
 Ca03 Li02 Ca03 98.9(3) . 2_656 ?
 Ca03 Li02 Ca04 100.5(3) 2_656 . ?
 Ca03 Li02 Ca04 80.3(2) . . ?
 Si03 Li02 Ca01 68.8(2) 2_656 . ?
 Si03 Li02 Ca02 139.7(4) 2_656 2_666 ?
 Si03 Li02 Ca02 67.86(17) 2_656 1_645 ?
 Si03 Li02 Ca03 142.6(4) 2_656 . ?
 Si03 Li02 Ca03 68.09(17) 2_656 2_656 ?
 Si03 Li02 Ca04 68.7(2) 2_656 . ?
 Si04 Li02 Ca01 144.9(4) 2_656 . ?
 Si04 Li02 Ca02 71.7(2) 2_656 2_666 ?
 Si04 Li02 Ca02 66.80(19) 2_656 1_645 ?
 Si04 Li02 Ca03 72.1(2) 2_656 . ?
 Si04 Li02 Ca03 67.62(18) 2_656 2_656 ?
 Si04 Li02 Ca04 147.2(4) 2_656 . ?
 Si04 Li02 Si03 127.0(3) 2_656 2_656 ?
 O01 Li02 Ca01 44.06(18) 1_655 . ?
 O01 Li02 Ca02 46.91(19) 1_655 2_666 ?
 O01 Li02 Ca02 75.5(3) 1_655 1_645 ?
 O01 Li02 Ca03 116.6(3) 1_655 . ?
 O01 Li02 Ca03 137.8(4) 1_655 2_656 ?
 O01 Li02 Ca04 107.1(3) 1_655 . ?
 O01 Li02 Si03 92.8(3) 1_655 2_656 ?
 O01 Li02 Si04 101.0(4) 1_655 2_656 ?
 O02 Li02 Ca01 126.3(4) . . ?
 O02 Li02 Ca02 95.2(3) . 1_645 ?
 O02 Li02 Ca02 48.8(2) . 2_666 ?
 O02 Li02 Ca03 47.6(2) . . ?
 O02 Li02 Ca03 95.6(3) . 2_656 ?
 O02 Li02 Ca04 127.3(4) . . ?
 O02 Li02 Si03 160.3(4) . 2_656 ?
 O02 Li02 Si04 33.27(15) . 2_656 ?
 O02 Li02 O01 92.5(4) . 1_655 ?
 O02 Li02 O03 92.1(4) . . ?
 O03 Li02 Ca01 105.7(3) . . ?
 O03 Li02 Ca02 115.9(3) . 2_666 ?
 O03 Li02 Ca02 141.8(4) . 1_645 ?
 O03 Li02 Ca03 79.5(3) . 2_656 ?
 O03 Li02 Ca03 47.16(19) . . ?
 O03 Li02 Ca04 43.69(18) . . ?
 O03 Li02 Si03 95.5(3) . 2_656 ?
 O03 Li02 Si04 103.5(4) . 2_656 ?
 O03 Li02 O01 141.6(4) . 1_655 ?
 O12 Li02 Ca01 95.5(3) 2_656 . ?
 O12 Li02 Ca02 139.2(5) 2_656 2_666 ?
 O12 Li02 Ca02 44.1(2) 2_656 1_645 ?
 O12 Li02 Ca03 43.5(2) 2_656 2_656 ?
 O12 Li02 Ca03 141.0(5) 2_656 . ?
 O12 Li02 Ca04 95.1(4) 2_656 . ?
 O12 Li02 Si03 31.58(16) 2_656 2_656 ?
 O12 Li02 Si04 95.5(3) 2_656 2_656 ?
 O12 Li02 O01 101.8(5) 2_656 1_655 ?
 O12 Li02 O02 128.7(5) 2_656 . ?
 O12 Li02 O03 104.7(5) 2_656 . ?
 Ca02 O01 Ca01 124.67(10) 2_566 1_455 ?
 Ca02 O01 Li02 84.4(2) 2_566 1_455 ?
 Si04 O01 Ca01 93.91(10) . 1_455 ?
 Si04 O01 Ca02 125.28(13) . 2_566 ?
 Si04 O01 Li02 135.9(2) . 1_455 ?
 Li02 O01 Ca01 92.6(2) 1_455 1_455 ?
 Ca03 O02 Ca02 105.93(9) . 2_666 ?
 Si04 O02 Ca02 124.29(12) 2_656 2_666 ?
 Si04 O02 Ca03 127.96(12) 2_656 . ?
 Si04 O02 Li02 102.2(3) 2_656 . ?
 Li02 O02 Ca02 89.1(3) . 2_666 ?
 Li02 O02 Ca03 90.4(3) . . ?
 Ca03 O03 Ca04 129.83(10) . . ?
 Ca03 O03 Li02 84.7(2) . . ?
 Si04 O03 Ca03 124.76(13) . . ?
 Si04 O03 Ca04 93.22(10) . . ?
 Si04 O03 Li02 130.8(2) . . ?
 Li02 O03 Ca04 94.0(2) . . ?
 Ca02 O04 Ca03 98.39(8) . 2_666 ?
 Ca03 O04 Ca02 99.62(8) . . ?
 Ca03 O04 Ca03 98.21(8) . 2_666 ?
 Si01 O04 Ca02 129.92(12) 2_666 . ?
 Si01 O04 Ca03 112.33(11) 2_666 2_666 ?
 Si01 O04 Ca03 113.20(11) 2_666 . ?
 Ca02 O05 Ca02 99.92(8) . 2_566 ?
 Ca02 O05 Ca03 93.05(8) 2_566 . ?
 Ca02 O05 Ca03 98.70(8) . . ?
 Si02 O05 Ca02 131.00(12) . 2_566 ?
 Si02 O05 Ca02 115.35(12) . . ?
 Si02 O05 Ca03 112.67(11) . . ?
 Ca01 O06 Ca01 104.22(8) 1_455 2_665 ?
 Ca01 O06 Ca04 93.82(8) 1_455 . ?
 Ca01 O06 Ca04 101.53(8) 2_665 . ?
 Si02 O06 Ca01 105.96(11) . 2_665 ?
 Si02 O06 Ca01 132.66(12) . 1_455 ?
 Si02 O06 Ca04 114.50(12) . . ?
 Ca01 O07 Ca04 103.04(8) . 2_665 ?
 Ca01 O07 Ca04 99.76(9) . . ?
 Ca04 O07 Ca04 101.16(8) . 2_665 ?
 Si01 O07 Ca01 131.79(13) . . ?
 Si01 O07 Ca04 117.96(12) . . ?
 Si01 O07 Ca04 98.11(11) . 2_665 ?
 Ca04 O08 Ca01 98.34(8) . 1_455 ?
 Si04 O08 Ca01 93.38(10) . 1_455 ?
 Si04 O08 Ca04 95.17(10) . . ?
 Si04 O08 Li01 126.9(3) . 1_545 ?
 Li01 O08 Ca01 115.3(3) 1_545 1_455 ?
 Li01 O08 Ca04 121.2(3) 1_545 . ?
 Si02 O09 Ca01 79.90(9) 2_566 1_456 ?
 Si02 O09 Si03 133.18(15) 2_566 . ?
 Si02 O09 Li01 89.6(2) 2_566 2_566 ?
 Si03 O09 Ca01 125.13(12) . 1_456 ?
 Si03 O09 Li01 130.3(2) . 2_566 ?
 Li01 O09 Ca01 79.03(18) 2_566 1_456 ?
 Si01 O10 Ca04 83.09(10) 2_666 1_556 ?
 Si01 O10 Si03 137.01(16) 2_666 . ?
 Si03 O10 Ca04 131.24(12) . 1_556 ?
 Ca04 O11 Ca01 95.75(8) . . ?
 Si03 O11 Ca01 121.53(12) 2_656 . ?
 Si03 O11 Ca04 124.80(12) 2_656 . ?
 Si03 O11 Li01 106.4(2) 2_656 2_665 ?
 Li01 O11 Ca01 100.4(2) 2_665 . ?
 Li01 O11 Ca04 104.6(3) 2_665 . ?
 Ca03 O12 Ca02 94.20(8) . 2_566 ?
 Si03 O12 Ca02 121.51(12) . 2_566 ?
 Si03 O12 Ca03 123.53(12) . . ?
 Si03 O12 Li02 109.7(3) . 2_656 ?
 Li02 O12 Ca02 102.1(3) 2_656 2_566 ?
 Li02 O12 Ca03 102.4(3) 2_656 . ?
 Si01 O13 Si02 143.90(16) . . ?
 Si01 O13 Li01 114.6(3) . . ?
 Si02 O13 Li01 101.3(3) . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  2.708
_oxdiff_exptl_absorpt_empirical_full_min  0.253
