# Three-dimensional graphene nanoribbons as a framework for molecular assembly and local probe chemistry

https://mdr.nims.go.jp/datasets/ffe0e1ea-c5ea-4ab7-935a-7a15704a89b2

## File

- [20200228 sciadv.aay8913.pdf](https://mdr.nims.go.jp/filesets/e668a21f-2959-48ea-adfc-f48c3d0ba9f0/download) ([Detail](https://mdr.nims.go.jp/filesets/e668a21f-2959-48ea-adfc-f48c3d0ba9f0.md))

## Id

ffe0e1ea-c5ea-4ab7-935a-7a15704a89b2

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2023-12-25T00:31:00.683155Z

## Updated at

2024-01-05T13:14:10.686655Z

## Published at

2023-12-28T07:30:36.001556Z

## Doi



## First published url

https://doi.org/10.1126/sciadv.aay8913

## Date published

2020-02-28

## Recorded date published

2020-2-28

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Three-dimensional graphene nanoribbons as a framework for molecular assembly
    and local probe chemistry
  title_type: original
  lang: en

## Description

- description: Recent advances in state-of-the-art probe microscopy allow us to conduct
    single molecular chemistry via tip-induced reactions and direct imaging of the
    inner structure of the products. Here, we synthesize three-dimensional graphene
    nanoribbons by on-surface chemical reaction and take advantage of tip-induced
    assembly to demonstrate their capability as a playground for local probe chemistry.
    We show that the radical caused by tip-induced debromination can be reversibly
    terminated by either a bromine atom or a fullerene molecule. The experimental
    results combined with theoretical calculations pave the way for sequential reactions,
    particularly addition reactions, by a local probe at the single-molecule level
    decoupled from the surface.
  description_type: abstract
  lang: en

## Creator

- name: Shigeki Kawai
  role: author
  orcid: https://orcid.org/0000-0003-2128-0120
  organization: National Institute for Materials Science
- name: Ondřej Krejčí
  role: author
  orcid: https://orcid.org/0000-0002-4948-4312
  organization: Aalto University
- name: Tomohiko Nishiuchi
  role: author
  orcid: https://orcid.org/0000-0002-2113-0731
  organization: Osaka University
- name: Keisuke Sahara
  role: author
  organization: Osaka University
  department: Department of Chemistry, Graduate School of Science
- name: Takuya Kodama
  role: author
  orcid: https://orcid.org/0000-0001-8275-2393
  organization: Osaka University
- name: Rémy Pawlak
  role: author
  orcid: https://orcid.org/0000-0001-8295-7241
  organization: Universität Basel
- name: Ernst Meyer
  role: author
  orcid: https://orcid.org/0000-0001-6385-3412
  organization: University of Basel
- name: Takashi Kubo
  role: author
  orcid: https://orcid.org/0000-0001-6809-7396
  organization: Osaka University
- name: Adam S. Foster
  role: author
  orcid: https://orcid.org/0000-0001-5371-5905
  organization: Aalto University

## Contact agent



## Publisher

organization: American Association for the Advancement of Science (AAAS)

## Managing organization



## Keyword

- subject: local probe
  schema: not_defined
- subject: graphene nanoribbons
  schema: not_defined
- subject: molecular assembly
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by-nc/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Science Advances
  issn: '23752548'
  volume: '6'
  issue: '9'
  article_number: eaay8913

## Conference



## Related item



## Funding

- identifier: '834402'
  funder_name: H2020 European Research Council
- identifier: 19H00856
  funder_name: JSPS
- identifier: 18K19004
  funder_name: JSPS

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## Fileset

- id: e668a21f-2959-48ea-adfc-f48c3d0ba9f0
  filename: 20200228 sciadv.aay8913.pdf
  content_type: application/pdf
  size: 670578
  md5: f751e22aeb447acf2ef0c66723d659d1

## Thumbnail

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filename: 20200228 sciadv.aay8913.pdf