# Macroscopic Structural Transition of Nickel Dithiolate Capsule with Uniaxial Magnetic Anisotropy in Water

https://mdr.nims.go.jp/datasets/f7fab68c-36ad-4dfc-bc97-a6fa7d8b4db6

## File

- [Advanced Science - 2025 - Fujino - Macroscopic Structural Transition of Nickel Dithiolate Capsule with Uniaxial Magnetic.pdf](https://mdr.nims.go.jp/filesets/407e56ca-c311-4a36-8391-e55d2fdf1193/download) ([Detail](https://mdr.nims.go.jp/filesets/407e56ca-c311-4a36-8391-e55d2fdf1193.md))

## Id

f7fab68c-36ad-4dfc-bc97-a6fa7d8b4db6

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-08-07T18:59:08.777187Z

## Updated at

2025-08-18T07:30:27.301632Z

## Published at

2025-08-18T07:21:32.804661Z

## Doi



## First published url

https://doi.org/10.1002/advs.202504967

## Date published

2025-04-23

## Recorded date published

2025-8

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Macroscopic Structural Transition of Nickel Dithiolate Capsule with Uniaxial
    Magnetic Anisotropy in Water
  title_type: original
  lang: en

## Description

- description: Dynamic soft materials incorporating open-shell molecules offer immense
    potential for applications that require tunable magnetic properties. However,
    achieving this potential necessitates balancing the long-range order, which is
    crucial for controlled magnetic interactions, with the inherent flexibility of
    soft matter. In this study, we introduce an amphiphilic d/π-conjugated nickel
    dithiolate radical anion that self-assembles into ordered structures, exhibiting
    reversible, temperature-dependent magnetic and structural transitions. These assemblies
    exhibit uniaxial magnetic anisotropy, which is rare in organic soft systems and
    has exceptional aqueous stability. This molecular design effectively balances
    the order, flexibility, and stability, addressing the key limitations of traditional
    soft materials.  Our findings provide crucial insights into spin–spin interactions
    in organized systems and establish a versatile platform for various applications
    including nanomedicine and stimuli-responsive materials.
  description_type: abstract
  lang: und

## Creator

- name: Tomoko Fujino
  role: author
  orcid: https://orcid.org/0000-0002-0441-8653
- name: Mafumi Hishida
  role: author
  orcid: https://orcid.org/0000-0003-4511-4039
- name: Masatoshi Ito
  role: author
- name: Toshikazu Nakamura
  role: author
  orcid: https://orcid.org/0000-0001-8672-0946
- name: Mizue Asada
  role: author
  orcid: https://orcid.org/0000-0003-0837-7753
- name: Naoya Kurahashi
  role: author
  orcid: https://orcid.org/0000-0002-9266-4837
- name: Hisao Kiuchi
  role: author
  orcid: https://orcid.org/0000-0001-9139-8218
- name: Yoshihisa Harada
  role: author
- name: Koji Harano
  role: author
  orcid: https://orcid.org/0000-0001-6800-8023
- name: Rie Makiura
  role: author
  orcid: https://orcid.org/0000-0003-2589-0698
- name: Kanokwan Jumtee Takeno
  role: author
  orcid: https://orcid.org/0000-0002-4087-7910
- name: So Yokomori
  role: author
  orcid: https://orcid.org/0000-0002-3472-3368
- name: Hiroshi Oike
  role: author
  orcid: https://orcid.org/0000-0001-6866-7774
- name: Hatsumi Mori
  role: author

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: electronic structure
  schema: not_defined
- subject: magnetic properties
  schema: not_defined
- subject: nanostructures
  schema: not_defined
- subject: synthesis design
  schema: not_defined
- subject: X-ray absorption spectroscopy
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin



## Embargo



## Journal

- title: Advanced Science
  issn: '21983844'
  volume: '12'
  issue: '29'
  article_number: '2504967'

## Conference



## Related item



## Funding

- funder_name: Kao Foundation for Arts and Sciences
- funder_name: Naito Foundation
- funder_name: Iketani Science and Technology Foundation
- identifier: JPMJPR22Q8
  funder_name: Japan Science and Technology Corporation
- identifier: JPMJPR21Q2
  funder_name: Japan Science and Technology Corporation

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 407e56ca-c311-4a36-8391-e55d2fdf1193
  filename: Advanced Science - 2025 - Fujino - Macroscopic Structural Transition of
    Nickel Dithiolate Capsule with Uniaxial Magnetic.pdf
  content_type: application/pdf
  size: 3299871
  md5: 1eca0b75891e0c47c2140407275ba620

## Thumbnail

fileset_id: 407e56ca-c311-4a36-8391-e55d2fdf1193
filename: Advanced Science - 2025 - Fujino - Macroscopic Structural Transition of
  Nickel Dithiolate Capsule with Uniaxial Magnetic.pdf