# Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the Latest Experimental Phase Diagram

https://mdr.nims.go.jp/datasets/f54cb2cb-afec-4245-b6cb-f74d5766b78b

## File

- [Manuscript_JPED-TBM_IOhnuma_v3.pdf](https://mdr.nims.go.jp/filesets/193c9ac3-81f9-4ee7-bb08-0fa5deb296bd/download) ([Detail](https://mdr.nims.go.jp/filesets/193c9ac3-81f9-4ee7-bb08-0fa5deb296bd.md))
- [Tables.pdf](https://mdr.nims.go.jp/filesets/2e6efeb9-fb44-416a-befe-3c24e64173e5/download) ([Detail](https://mdr.nims.go.jp/filesets/2e6efeb9-fb44-416a-befe-3c24e64173e5.md))
- [Figures.pdf](https://mdr.nims.go.jp/filesets/4984aa70-f123-4acd-a837-361bdf9a5b30/download) ([Detail](https://mdr.nims.go.jp/filesets/4984aa70-f123-4acd-a837-361bdf9a5b30.md))

## Id

f54cb2cb-afec-4245-b6cb-f74d5766b78b

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-12-25T07:31:48.725015Z

## Updated at

2025-05-04T23:30:07.032128Z

## Published at

2025-05-04T23:19:03.423944Z

## Doi

https://doi.org/10.48505/nims.5229

## First published url

https://doi.org/10.1007/s11669-024-01110-1

## Date published

2024-05-05

## Recorded date published

2024-6

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the
    Latest Experimental Phase Diagram
  title_type: original
  lang: en

## Description

- description: The phase diagram of the Fe-Zn binary system was evaluated based on
    the CALPHAD method with reference to the latest experimental data. The solubility
    ranges of the intermetallic compound (IMC) phases, Γ-Fe4Zn9, Γ1-Fe11Zn40, δ1k-FeZn7,
    δ1p- Fe13Zn126, and ζ-FeZn13 were modeled considering their structures consisting
    of Zn12 icosahedra with Fe at the center (Fe1Zn12 clusters) as well as glue-like
    Fe and Zn atoms, and the miscibility gap between the δ1k and δ1p phases was also
    taken into account in the present calculations. The solubility of Fe in the liquid
    and (ηZn) phases that was confirmed as dozens of times larger than the values
    reported in the earlier literature could be calculated by introducing Fe1Zn12
    associates to these solution phases. Consequently, all phase equilibria were adequately
    reproduced by the thermodynamic models and parameters revised in the present study.
  description_type: abstract
  lang: und

## Creator

- name: Ikuo Ohnuma
  role: author
  orcid: https://orcid.org/0000-0003-4874-4941
- name: Kwangsik Han
  role: author
- name: Inho Lee
  role: author
- name: Takako Yamashita
  role: author
- name: Ryosuke Kainuma
  role: author

## Contact agent



## Publisher

organization: Springer Science and Business Media LLC

## Managing organization



## Keyword

- subject: CALPHAD
  schema: not_defined
- subject: phase equilibria
  schema: not_defined
- subject: hot-dip galvanizing
  schema: not_defined
- subject: thermodynamics
  schema: not_defined

## Rights

- description: 'This version of the article has been accepted for publication, after
    peer review (when applicable) and is subject to Springer Nature’s AM terms of
    use, but is not the Version of Record and does not reflect post-acceptance improvements,
    or any corrections. The Version of Record is available online at: https://doi.org/10.1007/s11669-024-01110-1'
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-05-05
end_date: 2025-05-05

## Journal

- title: Journal of Phase Equilibria and Diffusion
  issn: '15477037'
  volume: '45'
  start_page: 537
  end_page: 546

## Conference



## Related item



## Funding

- identifier: 21H01676
  funder_name: JSPS
  description: 構造材料の結晶粒界・転位偏析計算システムの構築と偏析デザインによる組織制御

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## Measurement method



## Specimen



## Chemical composition



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## Fileset

- id: 193c9ac3-81f9-4ee7-bb08-0fa5deb296bd
  filename: Manuscript_JPED-TBM_IOhnuma_v3.pdf
  content_type: application/pdf
  size: 226039
  md5: 7a830e924331c7bc0af853c1eb7f1588
- id: 2e6efeb9-fb44-416a-befe-3c24e64173e5
  filename: Tables.pdf
  content_type: application/pdf
  size: 166977
  md5: 4c877b086879178cad8e748c3ea153c5
- id: 4984aa70-f123-4acd-a837-361bdf9a5b30
  filename: Figures.pdf
  content_type: application/pdf
  size: 1271324
  md5: 292a9514f9010fc911daa75bade9a929

## Thumbnail

fileset_id: 193c9ac3-81f9-4ee7-bb08-0fa5deb296bd
filename: Manuscript_JPED-TBM_IOhnuma_v3.pdf