# Efficient Room‐Temperature Methane Oxidation by μ‐Nitrido‐Bridged Iron Phthalocyanine Dimer Deposited on Conductive Carbon Black

https://mdr.nims.go.jp/datasets/f52eddf9-5fe4-4566-8c95-f199f9891359

## File

- [ChemCatChem - 2026 - Yamada - Efficient Room‐Temperature Methane Oxidation by  ‐Nitrido‐Bridged Iron Phthalocyanine Dimer.pdf](https://mdr.nims.go.jp/filesets/ab45c15d-aa95-4717-b06c-5204d75ce62e/download) ([Detail](https://mdr.nims.go.jp/filesets/ab45c15d-aa95-4717-b06c-5204d75ce62e.md))

## Id

f52eddf9-5fe4-4566-8c95-f199f9891359

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2026-02-01T14:17:23.728591Z

## Updated at

2026-02-02T07:30:07.474848Z

## Published at

2026-02-02T04:53:09.615488Z

## Doi



## First published url

https://doi.org/10.1002/cctc.202501356

## Date published

2026-01-31

## Recorded date published

2026-2

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Efficient Room‐Temperature Methane Oxidation by μ‐Nitrido‐Bridged Iron Phthalocyanine
    Dimer Deposited on Conductive Carbon Black
  title_type: original
  lang: en

## Description

- description: Appropriate deposition of metal complex-based catalysts on solid carriers
    sometimes results in considerably higher catalytic activity than that of the metal
    complex alone, due to interactions between the complex and solid. These catalysts
    could be a part of single-molecule catalysts (SMCs) or site-isolated molecular
    complex catalysts (SIMCs). Herein, we report a solid-supported metal complex catalyst
    for CH4 oxidation at room temperature. Specifically, µ-nitrido-bridged iron phthalocyanine
    dimer deposited on conductive carbon black can oxidatively activate the chemically
    stable C–H bond of CH4 with high efficiency even at 25 °C in an aqueous solution
    containing H2O2 as an oxidant. Its catalytic activity for CH4 oxidation is much
    higher than that of commonly used Fenton reaction with Fe2+ and H2O2 under the
    same conditions. Such high catalytic oxidizing activity is attributable to the
    interaction between the specific surface sites of carbon black and the high-valent
    iron-oxo species of the catalyst molecule.
  description_type: abstract
  lang: und

## Creator

- name: Yasuyuki Yamada
  role: author
- name: Akiko Sakata
  role: author
- name: Yuka Toyoda
  role: author
- name: Chaoqi Chen
  role: author
- name: Satoshi Muratsugu
  role: author
- name: Yutaka Hitomi
  role: author
- name: Kin‐ichi Oyama
  role: author
- name: Akiyoshi Kuzume
  role: author
- name: Koji Harano
  role: author
  orcid: https://orcid.org/0000-0001-6800-8023
- name: Mizuki Tada
  role: author
- name: Kentaro Tanaka
  role: author

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: μ-nitrido-bridged dimer
  schema: not_defined
- subject: carbon substrate
  schema: not_defined
- subject: iron phthalocyanine
  schema: not_defined
- subject: methane oxidation
  schema: not_defined
- subject: scanning transmission electron microscopy
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: ChemCatChem
  issn: '18673880'
  volume: '18'
  issue: '3'
  article_number: e01356

## Conference



## Related item



## Funding

- identifier: JP23H04874
  funder_name: JSPS
  description: メゾヒエラルキーの映像分子科学

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: ab45c15d-aa95-4717-b06c-5204d75ce62e
  filename: ChemCatChem - 2026 - Yamada - Efficient Room‐Temperature Methane Oxidation
    by  ‐Nitrido‐Bridged Iron Phthalocyanine Dimer.pdf
  content_type: application/pdf
  size: 1702547
  md5: 2609868d2f64b52b9c04633ccda8ebed

## Thumbnail

fileset_id: ab45c15d-aa95-4717-b06c-5204d75ce62e
filename: ChemCatChem - 2026 - Yamada - Efficient Room‐Temperature Methane Oxidation
  by  ‐Nitrido‐Bridged Iron Phthalocyanine Dimer.pdf