# Effect of borate substitution on zinc phosphate glasses

https://mdr.nims.go.jp/datasets/f5123d7a-30c3-4665-a159-e6f6fb5f6894

## File

- [133_24096.pdf](https://mdr.nims.go.jp/filesets/beba1168-a934-4997-b0ce-dc582fe30051/download) ([Detail](https://mdr.nims.go.jp/filesets/beba1168-a934-4997-b0ce-dc582fe30051.md))

## Id

f5123d7a-30c3-4665-a159-e6f6fb5f6894

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-01-10T06:11:34.725212Z

## Updated at

2025-01-11T07:30:58.732191Z

## Published at

2025-01-20T03:31:08.662241Z

## Doi



## First published url

https://doi.org/10.2109/jcersj2.24096

## Date published

2025-01-01

## Recorded date published

2025

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Effect of borate substitution on zinc phosphate glasses
  title_type: original
  lang: en

## Description

- description: 'The combination of glass-forming oxides can induce phase separation
    at the atomic level, particularly when a mixture involves both ionic and covalent
    bonds. In this study, we report physical properties of B2O3-substituted ZnO–P2O5
    (ZP) glass and the substitution effect of B2O3 on the structure of ZP glasses
    via magic angle spinning nuclear magnetic resonance (MAS NMR), X-ray diffraction,
    small angle X-ray scattering, positron annihilation spectroscopy and inelastic
    light scattering measurements. At 5 mol% or less B2O3 substitution, an emerging
    of phase separation is not confirmed. On the contrary, at 10 mol% B2O3 substitution,
    three-coordinated boron formation is confirmed in 11B MAS NMR in addition to a
    correlation between the BO4/2 units. The substitution of a large amount of B2O3
    confirmed the local coordination change of zinc cations in addition to the formation
    of a cluster-like structure in the low-Q region via small angle X-ray scattering.
    The 11B and 31P MAS NMR results suggest that the coordination states of boron
    are affected by the number of bridging oxygen atoms in the substituted PO4 chain
    structure of the ZP glass. '
  description_type: abstract
  lang: und

## Creator

- name: Hirokazu Masai
  role: author
- name: Takahiro Ohkubo
  role: author
- name: Yohei Onodera
  role: author
  orcid: https://orcid.org/0000-0002-3080-6991
- name: Yasuhiro Fujii
  role: author
- name: Seiya Shimono
  role: author
- name: Akitoshi Koreeda
  role: author

## Contact agent



## Publisher

organization: Ceramic Society of Japan

## Managing organization



## Keyword

- subject: Glass
  schema: not_defined
- subject: Phosphate
  schema: not_defined
- subject: Borate
  schema: not_defined
- subject: Structure
  schema: not_defined
- subject: NMR
  schema: not_defined
- subject: Diffraction
  schema: not_defined
- subject: Inelastic light scattering
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Journal of the Ceramic Society of Japan
  issn: '13486535'
  volume: '133'
  issue: '1'
  article_number: '24096'

## Conference



## Related item



## Funding

- identifier: 18H01714
  funder_name: JSPS
  description: 'Scientific Research (B) '
- identifier: 22H01785
  funder_name: JSPS
  description: 'Scientific Research (B) '
- identifier: 21H01018
  funder_name: JSPS
  description: 'Scientific Research (B) '
- identifier: 19H05618
  funder_name: JSPS
  description: Scientific Research (S)
- identifier: 24K08045
  funder_name: JSPS
  description: Scientific Research (C)
- identifier: 20H05881
  funder_name: JSPS
  description: Transformative Research Areas (A)
- identifier: 20H05882
  funder_name: JSPS
  description: Transformative Research Areas (A)
- identifier: 23H04096
  funder_name: JSPS
  description: Transformative Research Areas (A)

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



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## Process for specimen treatment



## Computational method



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## Fileset

- id: beba1168-a934-4997-b0ce-dc582fe30051
  filename: 133_24096.pdf
  content_type: application/pdf
  size: 1151763
  md5: 4aae9da39b9ccae169af488c26b09954

## Thumbnail

fileset_id: beba1168-a934-4997-b0ce-dc582fe30051
filename: 133_24096.pdf