# Resistance Switch in a Minimal-Fullerene Chain in Vertically Stacked Electrodes

https://mdr.nims.go.jp/datasets/f3729642-664e-483a-8d02-81d14a323acc

## File

- [2_Maintext_Hirama2024.pdf](https://mdr.nims.go.jp/filesets/7a8ae74f-0d61-4e30-98fd-91800c0dc80e/download) ([Detail](https://mdr.nims.go.jp/filesets/7a8ae74f-0d61-4e30-98fd-91800c0dc80e.md))

## Id

f3729642-664e-483a-8d02-81d14a323acc

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-05-28T23:55:16.393357Z

## Updated at

2024-05-29T03:30:15.645419Z

## Published at

2024-05-29T03:30:16.086376Z

## Doi

https://doi.org/10.48505/nims.4524

## First published url

https://doi.org/10.1021/acsaelm.4c00219

## Date published

2024-05-28

## Recorded date published

2024-5-28

## Resource type

journal_article

## Manuscript type

authors_original

## Collection



## Title

- title: Resistance Switch in a Minimal-Fullerene Chain in Vertically Stacked Electrodes
  title_type: original
  lang: en

## Description

- description: 'A switch element with a minimal fullerene chain was prepared by spin
    coating a C60 pyrrolidine trisaccharide (CPTA) film between vertically stacked
    two metallic electrodes. In this structure, the nanoscale length of the fullerene
    chain can be adjusted by changing the thickness of the CPTA film by changing spin
    coating condition. The CPTA film had a rough surface that led to cause distance
    fluctuations between the two electrodes. At the thinnest point, a nanoscale chain
    could be selectively formed as a conductive channel that potentially exhibited
    binary resistance switching between high- and low-resistance states. This resistance
    change was primarily caused by the polymerization and depolymerization of the
    nanoscale C60 chain in response to external voltage inputs. When the film thickness
    was reduced to approximately 3.7 nm, corresponding to 3-4 fullerene chains bridging
    the two electrodes, a stable switching sequence was reproducibly achieved. '
  description_type: abstract
  lang: und

## Creator

- name: Takuma Hirama
  role: author
- name: Masato Takei
  role: author
  orcid: https://orcid.org/0000-0002-3522-0033
- name: Hiroyuki Motoyama
  role: author
- name: Masafumi Ohta
  role: author
- name: Hiroshi Suga
  role: author
  orcid: https://orcid.org/0000-0003-4333-4898
- name: Takatsugu Wakahara
  role: author
  orcid: https://orcid.org/0000-0002-6365-3215
- name: Kazuhito Tsukagoshi
  role: author
  orcid: https://orcid.org/0000-0001-9710-2692

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: fullerene
  schema: not_defined
- subject: polymerization
  schema: not_defined
- subject: C60 pyrrolidine tris-acid (CPTA)
  schema: not_defined
- subject: resistance switching
  schema: not_defined
- subject: vertically stacked structure
  schema: not_defined
- subject: nanochannel
  schema: not_defined
- subject: fullerene derivative
  schema: not_defined

## Rights

- description: This document is the unedited Author’s version of a Submitted Work
    that was subsequently accepted for publication in ACS Applied Electronic Materials,
    copyright © 2024 American Chemical Society after peer review. To access the final
    edited and published work see https://doi.org/10.1021/acsaelm.4c00219
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: ACS Applied Electronic Materials
  issn: '26376113'
  volume: '6'
  issue: '5'
  start_page: 3403
  end_page: 3408

## Conference



## Related item



## Funding

- identifier: 19H05460
  funder_name: Japan Society for the Promotion of Science
- identifier: 23K17869
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 7a8ae74f-0d61-4e30-98fd-91800c0dc80e
  filename: 2_Maintext_Hirama2024.pdf
  content_type: application/pdf
  size: 1070277
  md5: e9379357ccc38d71089437ce0aae03d5

## Thumbnail

fileset_id: 7a8ae74f-0d61-4e30-98fd-91800c0dc80e
filename: 2_Maintext_Hirama2024.pdf