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説明:

The lithium-ion transport mechanism in 0.7Li(CB9H10)–0.3Li(CB11H12) complex hydride solid electrolyte was studied over a wide time-scale (ns‒ms) by choosing appropriate techniques for assessing ionic motion on the desired time-scale using nuclear magnetic resonance (NMR) relaxation, AC impedance, and pulsed field gradient-NMR (PFG-NMR) measurements. The 7Li NMR linewidth decreased with increasing temperature, and the spin-lattice relaxation time T1 for the cation and anions showed a minimum near 303 K, indicating that the lithium ions and the anions were highly mobile. The activation energy estimated from the analysis of the NMR relaxation time matched well with the values estimated from the AC impedance and PFG-NMR. This confirms that the lithium-ion motion in 0.7Li(CB9H10)–0.3Li(CB11H12) is the same over a wide time-scale, suggesting steady Li-ion motion over a wide transport range. This understanding offers insights into strategies for designing complex hydride lithium superionic conductors.

権利情報:

• In Copyright
  

  This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry Letters, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpclett.4c00754

キーワード: Complex hydride, Lithium-ion conductors, ion dynamics, 7Li NMR, NMR relaxation

刊行年月日: 2024-05-09

出版者: American Chemical Society (ACS)

掲載誌:

• The Journal of Physical Chemistry Letters (ISSN: 19487185) p. 4864-4871

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4665

公開URL: https://doi.org/10.1021/acs.jpclett.4c00754

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更新時刻: 2025-05-09 08:30:43 +0900

MDRでの公開時刻: 2025-05-09 08:19:33 +0900