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The oxide-ion conductor Ba3MoNbO8.5, the oxide-ion and proton conductor Ba7Nb4MoO20, and their hexagonal perovskite-related oxides are important groups of materials because of their high ionic conductivity. The structure of the ion-conducting layer of these materials has not been clarified because of their complex structure and the difficulty in distinguishing between Mo and Nb. In this study, we separately detected 95Mo and 93Nb by solid-state nuclear magnetic resonance (NMR) measurements to directly observe the Mo/Nb coordination in the high-oxide-ion conductor Ba3MoNbO8.5. The results showed that the number of revealed peaks was different for 93Nb and 95Mo. For the two chemical shifts from 93Nb NMR, the more intense peak was attributed to a NbO6 octahedron in the conducting layer, while the less intense peak was ascribed to a NbO4 tetrahedron in the conducting layer or a NbO6 octahedron in the nonconducting layer. Four peaks were observed in the 95Mo NMR of the 95Mo-enriched sample. One peak was attributed to the MoO6 octahedron in the nonconducting layer. The other three peaks attributed to the conducting layer were only interpreted by assigning either one or two of them to the MoO5 polyhedra, which are speculated to play an important role in ionic conduction. Presumably, these are the first results supporting the presence of MoO5 in the ion-conducting layer of oxide-ion conductors, and Mo likely plays an important role in ionic conduction. The analysis of the local structure of Mo and Nb oxide polyhedra by NMR is an important tool for understanding the nature of ionic conduction because it provides element-independent information. It is therefore expected to contribute to the further development of oxide-ion conductors.

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• In Copyright
  This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journalof Physical Chemistry C, copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpcc.2c03429

Keyword: Fuel Cell, Gas Sensor, Oxygen Separation

Date published: 2022-08-11

Publisher: American Chemical Society (ACS)

Journal:

• The Journal of Physical Chemistry C (ISSN: 19327447) vol. 126 issue. 31 p. 13284-13290

Funding:

• Ministry of Education, Culture, Sports, Science and Technology JPMXP09A19NM0110

Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.4417

First published URL: https://doi.org/10.1021/acs.jpcc.2c03429

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Updated at: 2024-12-23 09:18:21 +0900

Published on MDR: 2024-12-23 12:30:34 +0900