# Polymerization Order in the Synthesis of 2D Block Supramolecular Copolymers

https://mdr.nims.go.jp/datasets/e911a77a-4b8e-4757-ab8f-021ecd5a80b9

## File

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## Id

e911a77a-4b8e-4757-ab8f-021ecd5a80b9

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-08-25T04:39:21.873003Z

## Updated at

2025-08-25T05:35:12.390968Z

## Published at

2026-07-20T23:29:33.887727Z

## Doi

https://doi.org/10.48505/nims.5670

## First published url

https://doi.org/10.1002/chem.202501739

## Date published

2025-08-13

## Recorded date published

2025-8-13

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Polymerization Order in the Synthesis of 2D Block Supramolecular Copolymers
  title_type: original
  lang: en

## Description

- description: It is shown that, as in the case of block copolymerization in covalent
    polymer chemistry, the order of the polymerization of two monomers has a critical
    effect in the synthesis of 2D block copolymers of porphyrin-based monomers. In
    one of the orders of polymerization, secondary nucleation is involved, leading
    to nanosheets with uncontrolled areas and edge roughness.
  description_type: abstract
  lang: und

## Creator

- name: Zhehui Jin
  role: author
- name: Masayuki Takeuchi
  role: author
  orcid: https://orcid.org/0000-0002-0207-0665
- name: Yutaka Wakayama
  role: author
  orcid: https://orcid.org/0000-0002-0801-8884
- name: Kazunori Sugiyasu
  role: author
  orcid: https://orcid.org/0000-0001-5699-2772

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: supramolecular polymerization
  schema: not_defined
- subject: block copolymerization
  schema: not_defined

## Rights

- description: " This is the peer reviewed version of the following article: Jin,
    Z., Takeuchi, M., Wakayama, Y. and Sugiyasu, K. (2025), Polymerization Order in
    the Synthesis of 2D Block Supramolecular Copolymers. Chem. Eur. J., 31: e01739,
    which has been published in final form at https://doi.org/10.1002/chem.202501739.
    This article may be used for non-commercial purposes in accordance with Wiley
    Terms and Conditions for Use of Self-Archived Versions. This article may not be
    enhanced, enriched or otherwise transformed into a derivative work, without express
    permission from Wiley or by statutory rights under applicable legislation. Copyright
    notices must not be removed, obscured or modified. The article must be linked
    to Wiley’s version of record on Wiley Online Library and any embedding, framing
    or otherwise making available the article or pages thereof by third parties from
    platforms, services and websites other than Wiley Online Library must be prohibited."
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2025-07-21
end_date: 2026-07-21

## Journal

- title: Chemistry – A European Journal
  issn: '09476539'
  volume: '31'
  issue: '45'
  article_number: e01739

## Conference



## Related item



## Funding

- funder_name: Samco Foundation
- funder_name: Mitsubishi Foundation
- funder_name: Sekisui Chemical
- identifier: JPMJCR23L2
  funder_name: Japan Science and Technology Corporation

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## Fileset

- id: 12a14684-24f3-46b9-8026-7eff7aa36ea4
  filename: JinZhehui.pdf
  content_type: application/pdf
  size: 1500485
  md5: 0242dff89b19bdb28972c5fe4f9c8394
- id: 66c186ce-42cf-4d1d-a4db-2d16c6af0cdd
  filename: suppmat.pdf
  content_type: application/pdf
  size: 2028630
  md5: 25218ad44de29327659c007c33142997

## Thumbnail

fileset_id: 12a14684-24f3-46b9-8026-7eff7aa36ea4
filename: JinZhehui.pdf