# Enhanced Reversibility of Mg Plating/Stripping via Solvation Sheath Regulation by a Multidentate Linear Oligoether

https://mdr.nims.go.jp/datasets/e900901c-f60f-44f9-ac37-e1c9c04817c8

## File

- [85_Mandai_Bat Supcap 2025_Enhanced electrochemistry of Mg by G6.pdf](https://mdr.nims.go.jp/filesets/be0eaaf1-71b2-409f-bc0f-95d015590519/download) ([Detail](https://mdr.nims.go.jp/filesets/be0eaaf1-71b2-409f-bc0f-95d015590519.md))

## Id

e900901c-f60f-44f9-ac37-e1c9c04817c8

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2025-10-10T14:29:21.224590Z

## Updated at

2025-10-21T07:06:07.238046Z

## Published at

2025-10-21T06:43:27.740798Z

## Doi



## First published url

https://doi.org/10.1002/batt.202500348

## Date published

2025-09-04

## Recorded date published

2025-10

## Resource type

journal_article

## Manuscript type

vor

## Collection



## Title

- title: Enhanced Reversibility of Mg Plating/Stripping via Solvation Sheath Regulation
    by a Multidentate Linear Oligoether
  title_type: original
  lang: en

## Description

- description: In this study, the effects of multidentate oligoether additives on
    the structural characteristics of weakly coordinated anion (WCA)-based electrolytes
    were examined. Integrating a linear oligoether of hexaglyme (G6) was found to
    be particularly effective at enhancing Mg plating/stripping performance, whereas
    the corresponding cyclic counterparts imparted inferior performance. The combined
    electrochemical and spectroscopic analyses suggested that changes in the coordination
    environments of Mg2+ in solution with a specific amount of G6 were responsible
    for the enhanced interfacial charge-transfer kinetics. The results of this study
    will help guide the design of fully ethereal RMMB electrolytes compatible with
    highly reactive Mg metal-negative electrodes.
  description_type: abstract
  lang: und

## Creator

- name: Toshihiko Mandai
  role: author
  orcid: https://orcid.org/0000-0002-2403-7794

## Contact agent



## Publisher

organization: Wiley

## Managing organization



## Keyword

- subject: electrolytes
  schema: not_defined
- subject: ether
  schema: not_defined
- subject: magnesium batteries
  schema: not_defined
- subject: multidentate
  schema: not_defined
- subject: solvation
  schema: not_defined

## Rights

- identifier: https://creativecommons.org/licenses/by/4.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo



## Journal

- title: Batteries & Supercaps
  issn: '25666223'
  volume: '8'
  issue: '10'
  article_number: '2500348'

## Conference



## Related item



## Funding

- identifier: JPMJPF2016
  funder_name: Center of Innovation Program
- identifier: JPMJGX23S1
  funder_name: Japan Science and Technology Agency

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: be0eaaf1-71b2-409f-bc0f-95d015590519
  filename: 85_Mandai_Bat Supcap 2025_Enhanced electrochemistry of Mg by G6.pdf
  content_type: application/pdf
  size: 2181012
  md5: 02d585fbe64ae1fb77ed58d798fc8a65

## Thumbnail

fileset_id: be0eaaf1-71b2-409f-bc0f-95d015590519
filename: 85_Mandai_Bat Supcap 2025_Enhanced electrochemistry of Mg by G6.pdf