# Direct bottom-up synthesis of ZnAl2O4 nanoparticle via organic ligand dissolution method

https://mdr.nims.go.jp/datasets/e6c9e3df-d8ae-4e0b-82c0-7f4862ebf8b8

## File

- [ZAO_OLD_AcceptedV2.pdf](https://mdr.nims.go.jp/filesets/7b78b850-f6de-4325-8e0d-0c46cd4cd5f2/download) ([Detail](https://mdr.nims.go.jp/filesets/7b78b850-f6de-4325-8e0d-0c46cd4cd5f2.md))

## Id

e6c9e3df-d8ae-4e0b-82c0-7f4862ebf8b8

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2023-12-01T07:06:13.657947Z

## Updated at

2024-12-24T04:59:12.955352Z

## Published at

2024-12-24T04:59:13.011923Z

## Doi

https://doi.org/10.48505/nims.5214

## First published url

https://doi.org/10.1007/s10853-023-08866-w

## Date published

2023-08-27

## Recorded date published

2023-9

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Direct bottom-up synthesis of ZnAl2O4 nanoparticle via organic ligand dissolution
    method
  title_type: original
  lang: en

## Description

- description: This study improves the hydrothermal synthesis of ZnAl2O4 to realize
    direct bottom-up chemical synthesis from a liquid precursor solution. The liquid
    solution was prepared by the organic ligand dissolution (OLD) method. Synthesized
    ZnAl2O4 was identified as a single phase comprising ZnAl2O4 with organic components
    speculated to work as surfactants that aid in size stabilization. The synthesized
    ZnAl2O4 product was observed to be in nanoparticle form, exhibiting a wide-bandgap
    attribute to the quantum size effect. The growth rate of ZnAl2O4 nanoparticles
    in the proposed method is low, and a series of results revealed the phase formation
    process of synthesized ZnAl2O4. This formation process seems common for chemically
    synthesized ZnAl2O4 and indicates the importance of compositional analysis in
    the study for chemical synthesis of this material. The application of the OLD
    method enables us to synthesize ZnAl2O4 across a wide pH range (3 ~ 11), and it
    is applicable to the continuous synthesis using a flow-type reaction system of
    hydrothermal reaction. Moreover, our technique is basically applicable to the
    synthesis of other spinel oxide. These characteristics of the OLD method are expected
    to extensively improve the investigation of chemical processing of spinel oxides.
  description_type: abstract
  lang: eng

## Creator

- name: Takayuki Nakane
  role: author
  orcid: https://orcid.org/0000-0003-0282-169X
  organization: National Institute for Materials Science
- name: Takashi Naka
  role: author
  orcid: https://orcid.org/0000-0002-0645-6952
  organization: National Institute for Materials Science
- name: Minako Nakayama
  role: author
  organization: National Institute for Materials Science
- name: Tetsuo Uchikoshi
  role: author
  orcid: https://orcid.org/0000-0003-3847-4781
  organization: National Institute for Materials Science

## Contact agent



## Publisher

organization: Springer Science and Business Media LLC

## Managing organization



## Keyword

- subject: Hydrothermal Synthesis
  schema: not_defined
- subject: Chemical Synthesis
  schema: not_defined
- subject: Nanoparticle
  schema: not_defined
- subject: ZnAl2O4, Spinel
  schema: not_defined

## Rights

- description: 'This version of the article has been accepted for publication, after
    peer review (when applicable) and is subject to Springer Nature’s AM terms of
    use, but is not the Version of Record and does not reflect post-acceptance improvements,
    or any corrections. The Version of Record is available online at: https://doi.org/10.1007/s10853-023-08866-w'
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2023-08-27
end_date: 2024-08-27

## Journal

- title: Journal of Materials Science
  issn: '15734803'
  volume: '58'
  start_page: 13269
  end_page: 13278

## Conference



## Related item



## Funding

- identifier: 16K13999
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



## Software



## Custom property



## Fileset

- id: 7b78b850-f6de-4325-8e0d-0c46cd4cd5f2
  filename: ZAO_OLD_AcceptedV2.pdf
  content_type: application/pdf
  size: 1851231
  md5: 999c336f04627a4ad223c248083dadd9

## Thumbnail

fileset_id: 7b78b850-f6de-4325-8e0d-0c46cd4cd5f2
filename: ZAO_OLD_AcceptedV2.pdf